Ti—Cr基合金的储氢性能及晶体结构.docVIP

Ti—Cr基合金的储氢性能及晶体结构 第42卷 2006年6月 第6期 641—646页 金属学腹 ACTAMETALLURGICASINICA ,,01.42 June2006 NO.6 PP.641-646 Ti—Cr基合金的储氢性能及晶体结构 汪洋 (兰州交通大学光电技术与智能控制教育部重点实验室,兰州730070) (浙江理工大学理学院,杭州310018) 张琰王新华陈长聘 (浙江大学金属材料研究所,杭州310027) 摘要研究了Til+Cr1.2Mn0.s(x=0.0,0.1,0.2,0.3)系和Til+Cr1.2Mn0.S—(M=Fe,Ni,Cu,V,VFe; x----0.0,0.1;y----0.1,0.3)系AB2型合金的储氢性能和晶体结构.xRD结果表明,合金主相为C14(MgZn2)型Laves 相,可以保证较高的吸,放氢量.通过A侧过化学计量以及B侧用Fle,Ni,Cu,V,VFe分别替代部分Mn,增加了点阵常 数和晶胞体积,降低了P—C—T曲线的滞后.由相应数据寻找出适合于金属氢化物氢压缩机的高压端储氢合金.结果表明,合金 TiCr1.2MD.0.5Feo.3与Til.1Cr1.2M110.sCUO.3具有良好的储氢性能和压缩特性,可以作为性能优良的高压端储氢合金. 关键词Ti—Cr基合金,储氢性能,晶体结构,压缩特性 中图法分类号TG139.7文献标识码A文章编号0412-1961(2006)06—0641—06 HYDRoGENSToRAGEPRoPERTIESANDCRYSTAL STRUCTUREoFTi—CrBASEDALLoYS WANGYanq KeyLaboratoryofPhotoelectricTechnologyandIntelligentControl,MinistryofEducation,LanzhouJiaotongUniversity, Lanzhou730070 CollegeofSciences,ZhejiangScience-TechnologyUniversity,Hangzhou310018 ZHANGYah,WANGXinhua,CHENChangpin InstituteofMetalMaterials,ZhejiangUniversity~Hangzhou310027 Correspondent:WANGyn,professor,Tel:(o931)4958o35,E-mail:wwyy$ool@ SupportedbyNationalMinistryofConstructionofChinaNo.05一K{一3) Manuscriptreceived2005-09--29.inrevisedform2006—02—20 ABSTRACTThehydrogenstoragepropertiesandcrystalstructuresofTil+xCr1. 2Mno.s(=0.0, 0.1,0.2,0.3)andTil+zCr1.2Mn0.8-y(M=Fe,Ni,Cu,V,VFe;x=0.0,0.1;y=0.1,0.3)havebeen studiedsystematically.XRDpatternsprovedthatthetwoseriesofhydrogenstoragealloyshavethe samecrystalstructure,C14(MgZn2)typedLavesphase,whichissuitableforhydrogenabsorptionand desorptionwithgreatamount.Thelatticeparametera,candcellvolumeVincreasewithincreasing TicontentandsubstitutionofMnbyFe,Ni,Cu,VandVFe,whilethehysteresisfactorsofP—C—T curvesdecrease.Inordertodevelophydrogenstoragealloysforthemetalhydridehydrogencompressor (MHHc),theeffectofthesubstitutionelementshavebeeninvestigated,andtheresultsshowthatboth alloys,TiCr1. 2Mn0. 5Fe0. 3andTil. 1Cr1. 2Mno. 5Cu0. 3,havehighhydrogenstoragecapacitiesandhigh compressionratios. KEYWoRDSTi_Crbasehydrogenstoragealloy,hydr