北京大学分析化学课件.pdfVIP

AgNO3 6.1 (p250) - NaCl(I ) 10 1mol/L AgI 8 0.1mol/L 10 6 6.2 2pAg 5.2 pAg 4.75 4 4.3 n 3.3 Ksp10 , 2 0.1mol/L npAg 1mol/L 0 0 50 100 150 200 T % 1 10 滴定突跃（pH pM’ ∆ϕ H+ ↔ OH- 2 Ag+ Cl- H+ A- 1 OH- HA Y M Ox Red OH- H A (分步) n 2 - - 6. 2 MohrCl Br AgNO (0.1mol/L) 3 K CrO (5%K CrO 1mL) 2 4 2 4 pH 6.5 ~ 10.5NH3pH 6.5 ~7.2 . H++CrO 2- Cr O 2- (K=4.3 1014) 4 2 7 Cl- - + Br Ag (?) (Ag A M (CrO ) m n m 4 n M (OH) - - n; I SCN