fe fe3si在熔锌作用下的腐蚀界面行为研究word格式论文.docxVIP

Fe，Fe3Si在熔锌作用下的腐蚀界面行为研究摘要液态锌对结构金属具有强烈的腐蚀性，极大的影响了热镀锌工业的质量和效益。液 锌腐蚀机理的研究对于有效地防止液态金属的腐蚀作用，延长热浸镀设备的使用寿命， 提高生产效率，具有较大的应用价值。本文研究了纯铁和铁基合金在液锌中的腐蚀。分析了液态锌中腐蚀后基体材料硬度 变化原因和液固两相的扩散及腐蚀层金属间化合物的生成过程，并探讨了纯铁在液态锌 中腐蚀的腐蚀机理。研究发现，纯铁在液锌中腐蚀过程主要是锌原子不断地向纯铁基体中扩散。在基体 中形成扩散层，并发生腐蚀反应形成腐蚀层。随着锌原子的扩散，引起了腐蚀层化学成 分的改变使腐蚀层熔点降低，从而最终导致扩散层由固相转变为液相。靠近腐蚀层的基 体部分的显微硬度降低主要是因为 Zn 原子向基体中的扩散，使基体体积膨胀，从而导 致表面层的张力为适应基体而变小，引起基体的硬度下降。通过不同Si含量的Fe3Si的腐蚀层生长动力学研究，腐蚀层的生长受扩散和界面反应 的联合控制：Zn原子沿着Fe3Si基体的晶界及空位的扩散，在基体中形成扩散层，并伴 随着界面反应。最终的腐蚀产物为ζ、δ和颗粒状的FeSi。由于化学计量比的Fe3Si存在 较高的空位浓度，其耐锌腐蚀性较低。关键词：液锌腐蚀，扩散，纯铁，界面反应，Fe3SiiRESEARCH ON CORROSION BEHAVIOR OF Fe AND Fe3Si IN LIQUID ZINCABSTRACTLiquid zinc has intensive corrosivity to structural metals, which greatly influence the quality and efficiency of the hot-dip galvanizing industry. The research on corrosion mechanism of liquid zinc has great applied value to prevent the liquid metal corrosion, to prolong the service life of hot-dip plating equipment and enhance production efficiency.In this paper, corrosions of iron and iron-base alloy in liquid zinc were studied. Reasons for the hardness variations of the corroded matrix materials were discussed. The diffusions of liquid-solid phase and the formation process of corrosion layer are analyzed. The corrosion mechanism of iron in liquid zinc was investigated.It was found that, the corrosion process of iron in liquid zinc was that zinc atoms diffused into iron substrate constantly and diffusion layer was formed during this process. The corrosion layer was configurated as the occurrence of corrosion reactions in the matrix. Moreover, chemical compounds changed with the diffusion of zinc atoms, which caused the decreasing of the melting point. As a result, diffusion layer was transformed from solid to liquid. The diffusion of zinc atoms was the main reason for the micohardness decrease of the matrix near the corrosion layer. The growth of iron volume resulted in the relaxation of the tensile stresses in the surface layer in order to apply to t