fenitio2ac粒子电极的制备及vis3def体系的研究word格式论文.docx

可见光光催化与3D/EF 有机结合组成Vis-3D/EF。主要研究成果如下：（1）通过优化Fe-Ni-TiO2/AC粒子电极的制备条件发现：浸渍液浓度2g/L，Fe-Ni掺杂比为5:5，Fe:Ni:TiO2摩尔比为0.5:0.5:100时得到的自制粒子电极在Vis-3D/EF体系光电催化性能最佳，具有明显的可见光催化和3D/EF 协同处理效果；（2）对Vis-3D/EF体系处理条件优化和动力学特点进行考察，得到最优处理条件下60min对20mg/L罗丹明B降解率为96.84%，反应过程更符合二级反应动力学特点，拟合度均在0.98以上；（3）将自制电极材料与常规电极材料组成的体系进行对比实验研究发现：Porous-TiO2阳极板和Fe-Ni-TiO2/AC粒子电极组成的体系降解过程具有明显的协同催化特点，协同因子达1.22，且处理能耗仅为常规石墨(Gr) 阳极、活性炭(AC)粒子电极组成体系的1/85.5，优势明显；（4）对Vis-3D/EF体系污染物降解机理进行了初步的研究和探讨发现：Vis-3D/EF 降解过程中电催化氧化作用、Fenton氧化作用、可见光催化作用以及可见光下的协同作用对罗丹明B去除率的贡献分别为43.88%、20.21%、15.26%和17.49%，·OH自由基对罗丹明B去除率的贡献为75.58%。协同作用的产生原因有三点：1）O2 可以作为光生电子的受体，减少了电子-空穴的复合，提高TiO2光催化降解效率；2）曝气提供了充足的溶解氧，促进光敏化作用产生活氧物质，进而高效降解染料；3）TiO2表面上的空穴-电子复合速率在电场作用下降低，提高了体系光电催化去除率。关键词：三维电极/电Fenton可见光光电催化粒子电极IITHEPREPARTIONOFFe-Ni-TiO2/ACPARTICLEELECTRODESANDTHESTUDYOFVis-3D/EFSYSTEMABSTRACTPhotocatalysisandelectrochemistrytechnologyhavebeenwidelyusedin organicwastewatertreatment.However,theapplicationofTiO2photocatalysis islimitedbecauseofitsdifficultseparation,easyrecombinationofphoto generationeletronandhole,and unabletoutilizevisible-light.Inthe electrochemistryfield,threedimensionelectrochemicalprocesshasbeen recognizedasaneffectivemethodbecauseofitshighcurrentefficiencyand treatmenteffect,buttheenergyconsumptionishigh.Three-dimension photoelectrocatalytictechnology,notonlysolvestheproblemsexistinginTiO2 photocatalysisprocess,butalsobreaksthelimitationsofelectrochemical process.However,thusfarlittleworkhasbeenreportedonthree-dimension photoelectrocatalytictechnology.Theapplicationofthevisibleirradiationand itscombinationtechniqueshasneverbeenreported.Sowehaveundertaken effortstoresearchavisibleirradiationassistedthree-dimensionalelectro-Fenton (Vis-3D/EF)systembycouplingvisiblelightphotocatalysisand three-dimensionalelectro-Fenton(3D/EF)inanundividedcell.PorousTiO2thin film(Porous-TiO2)electrodeandFe-Nico-dopingTiO2particlesloaded on activatedcarbon(Fe-Ni-TiO2/AC)wereusedasanodeandparticleelectrodes,respectively,plusgraphite(Gr)plateascathode,aeratio