金属钼表面mo-w-n-si系涂层的制备工艺与氧化性能分析-preparation process and oxidation performance analysis of mo - w - n - si coating on molybdenum surface.docxVIP

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金属钼表面mo-w-n-si系涂层的制备工艺与氧化性能分析-preparation process and oxidation performance analysis of mo - w - n - si coating on molybdenum surface.docx

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金属钼表面mo-w-n-si系涂层的制备工艺与氧化性能分析-preparation process and oxidation performance analysis of mo - w - n - si coating on molybdenum surface

(1) Mo-W-N-Si composite coating on the Mo substrate was made by in situ diffusion of Mo tungstening and then by ammonia nitriding and siliconizing. The coating showed there were two-tier structure.The outer layer was made of (Mo,W)Si2 and Si3N4 phases, and the inside layer was the transition layer made of Mo5Si3 phase. The best of preparation process was that Mo was tungstened at 1400 oC for 10 h, then nitrided at 1000 oC for 3 h and siliconzed at 1000 oC for 3 h. (2)Mo-W-N-Si composite coating had an excellent high-temperature oxidation resistance.The stable anti-oxidation life of the coating at 1300 oC, 1450 oC and 1600 oC were 2088 h, 1248 h and 288 h, respectively. The coating doped W could effectively inhibit the diffusion of Si. Additionally, Moderate amounts of Si3N4 were introduced into the MoSi2 which could effectively coordinate the heat matching performance between the Mo and MoSi2, which could improve the high temperature oxidation resistance of the coating.(3)Mo-W-N-Si composite coating had an excellent low-temperature oxidation resistance. The oxidation rates of Mo-W-N-Si composite coating at 500 oC and 600 oC in air were 0.0145 g/(m2×h) and 0.0191 g/(m2×h), respectively. This was attributed to a dense SiO2 film formed on the surface of Mo-W-N-Si composite coating on the Mo substrate.Keywords: Mo-W-N-Si composite coating, Pack cementation, Molybdenum, Anti-oxidation, Molybdenum electrodes目录摘要iAbstractii第一章绪论................................................................................................................................. 11.1 钼电极的简介 ................................................................................................................... 11.1.1 钼电极的发展 ......................................................................................................... 11.1.2 钼电极的使用现状 .................................................................................................. 21.2 钼电极的材料 .................................................