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prepared by sol-gel method. Through the XRD and Fluorescence spectrometry, it can be know that the La10(SiO4)6O3: Yb3+, Tm3+ calcined at 1200 ℃ has the strongest ultraviolet upconversion emission.After the Ultraviolet upconversion luminescence agent can be obtained, we choose the better sample composite with TiO2.The TiO2/Y2O3: Yb3+, Tm3+ composite photocatalyst have been synthesized bysol-gel method and precipitation method, respectively. Results from scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy dispersive spectroscopy (EDS) measurements demonstrate that TiO2 shells were formed on the upconversion luminescence agent by precipitation method. By fluorescence spectroscopy and photodegradation experiments, we know that the existence of this structure will not only improve the the upconversion emission, but also enhance the stability and photocatalytic efficiency. The relationship between the cumulate concentration of hydroxyl radical and degradation efficiency can be measured by spectrophotometry and fluorescence method. The results show that the photodegradation efficiency of TiO2 was affected by·OH concentration.The La10(SiO4)6O3: Yb3+, Tm3+/TiO2 and ZrO2: Yb3+, Tm3+ /TiO2 compositewere prepared by microwave method. By the photodegradation experiments, it can be known that since the presence of the upconversion luminescence agent, the composite can more easily decompose the stable organic pollutants. In addition, through repeated experiments, it can be konwn the sample which prepared by microwave method can also has good stability.Key Words: ultraviolet; upconversion luminescence; TiO2; core-shell; photocatalysis学位论文独创性声明 本人声明，所呈交的学位论文系在导师指导下本人独立完成的研究成果。 文中引用他人的成果，均已做出明确标注或得到许可。论文内容未包含法律意 义上已属于他人的任何形式的研究成果，也不包含本人已用于其他学位申请的 论文或成果，与我一同工作的同志对本研究所做的任何贡献均已在论文中作了 明确的说明并表示谢意。 论文作者签名： 日期： 年 月 日 学位论文知识产权权属声明本人在导师指导下所完成的论文及相关的职务作品，知识产权归属山东轻工业学院。山东轻工业学院享有以任何方式发表、复制、公开阅览、借阅以及 申请专利等权利，同意学校保留并向国家有关部门或机构送交论文的复印件和 电子版，本人离校后发表