利用沉淀法制备电子封装用硅微粉的分析-analysis of preparing silicon micropowder for electronic packaging by precipitation method.docxVIP

通过对环氧塑封料的线膨胀系数、导热系数、弹性模量、断面扫描、吸水率的性能测试，结果表明：当球形纳米 SiO2 填料占体系质量分数的 75%时，制备出的环氧塑封料的性 能最好(线膨胀系数为 33.81×10-6/K，导热系数为 0.427 W/m·k，弹性模量为 6.52GPa，Tg 为 161.67℃，吸水率为 0.16%)，基本可以满足电子封装材料的要求。关键词：高纯石英粉，高纯水玻璃，沉淀法，高纯球形纳米 SiO2，电子封装，环氧模塑 料AbstractWith the rapid development of the electronics industry, electronic packaging（the percentage of its sales for the entire electronics industry is 70%）has developed rapidly. Morethan 95% of Microelectronic devices are epoxy molding device, however epoxy molding device as packaging materials has its own problem. Epoxy resin’s coefficient of thermal expansion of epoxy resin does not match with coefficient of thermal expansion of the silicon integrated circuit chip. Epoxy molding compound which contains impurity ions can accelerate corrosion of the aluminum wire in the tube core, that will cause negative effect for the life of electronic components subject. To solve this problem and reduce the cost of epoxy molding compound(by adding a high filling amount of spherical silica), in this experiment, purity spherical nano-silica was obtained by improved precipitation and epoxy resin etc prepare epoxy molding compound by molding. The contents and conclusions of the experiment are as follows:In present, the need of making high purity spherical nano-silica can not be satisfied because of the lower purity industrial water glass, laboratory low modulus and low purity etc. In this study, the natural vein quartz was used as raw materials. By improving the traditionalpreparation method of making high-purity quartz powder（It is the first time to use of a smallpiece of vein quartz act as a medium ball milling method for avoiding to bring new impurity substance）established a reasonable purification route: coarse crushing→grinding→magnetic separation→ flotation→acid pickling→distilled water washing→settlement classification →drying, finally obtain high purity quartz powder. The test results by using scanning electron microscopy , X-ray powder diffracti