表面与界面化学试卷(a)2005.docVIP

武汉理工大学考试试题纸（ A 卷） 课程名称 表面与界面化学 专业班级 材化0301，0302 题号 一 二 三 四 五 六 七 八 九 十 总分 题分 24 23 10 10 9 12 12 100 备注: 学生不得在试题纸上答题(含填空题、选择题等客观题 Please explain the following terms: (3(8=24 points) ① surface tension ②CMC ③solubilisation ④ interface ⑤ coverage ⑥unit mesh ⑦surface atom density ⑧ surface activity Figure 1 shows a unit cell for a cubic crystal structure. ① Please find the Miller index for the shadow plane, calculate the face atom density, and plot its unit mesh. (15 points) ② If the latent heat of vaporization of the cubic solid is (Hv, Please estimate the surface energy for the shadow plane. (8 points) At 77K a 1.5g sample of a porous solid showed the following results for the adsorption of nitrogen: P (kPa) 4 20 V (cm3) (STP) 100 150 If the saturated vapor pressure and molecular area of nitrogen at this temperature are 100kPa and 16.2(10-20m2, respectively, calculate a specific surface area for the solid. (10 points) Figure 2 shows a number of adsorption isotherms (where a single isotherm is a coverage-pressure curve at a fixed temperature). Please determine the heat of adsorption at a given coverage. (10 points) Fig. 2 adsorption isotherms (1) Please give the conditions of contact angle for spreading wetting, adhesional wetting and immersional wetting. (6 points) (2) The HLB values for glyceryl monostearate and triethanolamine oleate are 3 and 12, respectively. Please point out which one is more soluble in oil? (3 points) During the CO oxidation on Pd(110) surface, the LEED pattern of O adsorption observed changes from Pd(110)c(2(4)O to Pd(110)(1(2)O with the temperature increase. Please draw the two LEED patterns and the possible real space overlayer structures for O on Pd(110). (Pd is a fcc metal). (12 points) At 20(C the surface tensions of water and n-octane are 72.8 and 21.8 mN(m-1, respectively, and the interfacial tension of the n-octane-water interface is 50.8mN(m-1. Calculate the work of adhesion betwe