芳香二羧酸稀土配位聚合物的合成结构及发光性能分析-synthesis structure and luminescent property analysis of aromatic dicarboxylic acid rare earth coordination polymer.docxVIP

AbstractSeven novel lanthanide coordination po lymers based on 2,4′–biphenyl– dicarboxylic acid (2,4′–H2bpdc), 1,4–benzenedicarboxylic acid (1,4–H2 BDC), and N,N′–bis(ethy lacetate)biimidazole (L) ligands from 2D layer to 3D network have been synthesized under hydro(solvo)thermal condit ions by changing the molar ratio between lant hanide nitrate and the ligands, pH value as well as the reaction solvent. The structures of these seven lant hanide coordination polymers are characterized by ele mental analyses, IR spectroscopy, and single–crystal X–ray diffraction. The luminescent properties of the complexes are characterized by fluorescent spectra.Aromatic mult icarboxylate acid such as 2,4′–H2bpdc and 1,4–H2 BDC are selected to react with lanthanide nitrate. Four 2D lanthanide coordination polymers (1~4) {[Ln(bpdc)(BDC)0.5(DMF) (H2O)]·1.5H2O}n [Ln=Sm(1), Tb(2), Dy(3), andGd(4)] were obtained. The results of single–crystal X–ray diffraction analysesind icates that complexes 1~4 are isostructural. The 2D layers are connected by bpdc2– and BDC2– ligands. They are stably stacked into 3D supermolecule via hydrogen bonds and p–π interactions.Single aromat ic dicarboxylate ligand 2,4′–H2 bpdc is used to synthesize 2D dysprosium–coordination polymer, it′s formula is [Dy(bpdc)(DMF)2(NO3 )3]n (5). From the topological view, complex 5 can be simplized (4,4) networks containing 8–ring channe ls, the pore size of the 8 –ring is 16.53×7.66?. A novel europium–coordinat ion polymer: [Eu(BDC)1.5(DMF)(H2O)]n (6) was constructed by 1,4–H2 BDC ligand under mixed solut ion of DMF and H2O. Sructural analyses ind icate that complex 6 displays 2–fold interpenetrating network of 3D framework.N,N′–bis(ethylacetate)biimidazole(L) is synthesized by 2,2′–biimidazole and ethyl bromoacetate under low temperature and characterized by IR spectroscopy and 1 H NMR spectra. The L ligand was used to synt hesis a novel terbium–coordinat ion polymer by regulat ing the pH value, whose molecul