改性13x,nay分子筛和丝光沸石对氯气吸附性能的分析-analysis of adsorption performance of modified 13x, nay molecular sieve and mordenite on chlorine gas.docxVIP

太原理 T 大学硕士研究生学位论 文STUDY OF CHLORINE ADSORPTION PROPERTIES ON MODIFIED 13X，Na Y AND MORDENITEMOLECULAR SIEVESABSTRACTChlorine is a very important basic chemical raw material in the chlor-alkali industry. Chlorine has been used extensiveJy in industriaJ ，agricultural and otherareas，and it is convenient for daily li fe and created wealth . As demands forchlorine increased ，there have been large amounts of chlorine gas in industrial.We have to wellhandle this problem otherwise it would endanger on human health，the growth of p)ants and animals and lead to the irreversible negative influence on the environmen t. The handling of chlorine-gases become a serious problem in industrial fields because the exhaust containing chlorine gas source is highly complex . Recently adopting soJid adsorbents have been a new ideaJmethod for adsorption-separation chlorine-gases，therefore，exploring a newefficient absorbent is a ve叩meaningful work.The research progress of chlorine adsorpt ion properties was reviewed. This paper studied the chJorine adsorption propertie s on 13X，NaY and mordenite mo)ecu)ar sieves before and after modified pretreatment with the P-C-Tapparatus. The stability of the three types of molecular sieves were characterized and analyzed by SEM，X-ray diffraction and F下IR spectroscopy.The main conclusions are as follo ing.lI1The characteristic IR bands of 13X，NaY and mordenite molecular sieves revealed that the existing framework structure of molecular sieves before and太原理工大学硕士研究生学位论文after modified pretreatment ，which can indicáte that the main structure rcmains unchanged af飞er the adsorption of chlorine. The characteristic IR peaks of NaY and mordenite zeolite shifted to a lower value a丘er chlorìne adsorption ， suggesting that the formation of complex compound of C204 2.with aluminium.After chlorine adsorption ，the diffraction peaks intensity of three types ofmodified pretreatment molecular sieves declined slightly，wh