干湿烟气循环方式对富氧燃煤锅炉热力特性及安全性影响-influence of dry and wet flue gas circulation modes on thermal characteristics and safety of oxygen-enriched coal-fired boilers.docxVIP
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干湿烟气循环方式对富氧燃煤锅炉热力特性及安全性影响-influence of dry and wet flue gas circulation modes on thermal characteristics and safety of oxygen-enriched coal-fired boilers
摘要富氧燃烧技术是新一代洁净煤发电技术,其烟气再循环系统包括干法、湿法两种,主要区别是锅炉的部分排烟是否经过干燥程序再通过再循环系统送入炉内,两种烟气循环方式各有利弊。本文以富氧燃煤锅炉为研究基础,试图将干/湿烟气循环式对富氧燃煤锅炉热力特性及安全性的影响进行深入研究,这对富氧燃煤锅炉以后的实际工程应用具有重要意义。以某电站600MW燃煤锅炉为例,研究了干/湿烟气循环下富氧燃煤锅炉的热力特性,与空气模式作对比分析,并从能量平衡角度对锅炉进行优化设计;采用混合气体重叠谱带改进模型计算了干/湿烟气循环下烟气中三原子气体发射率,并比较了与其他模型间的最大误差;基于不同循环方式下的烟气组分,首次探讨了再循环方式对锅炉尾部烟气酸露点的影响;针对常规空气锅炉不存在的磨煤机低温腐蚀问题,尝试研究讨论了富氧燃煤锅炉磨煤机的低温腐蚀特性。富氧燃烧下,再循环方式中脱硫脱水过程对烟气组分影响明显;与干烟气循环相比,湿烟气循环下的锅炉效率升高,燃煤量降低;优化后的总受热面积减少,可降低部分初投资;混合气体重叠谱带改进模型与逐线计算精度模型、灰体加权和模型吻合较好,最大偏差仅为10.0%、17.4%;在不同温度、不同路径长度下,湿烟气循环下的烟气发射率均大于其干烟气循环下;富氧燃烧下的烟气酸露点比空气状况下高很多,其中,采用湿烟气循环时,锅炉尾部设备低温腐蚀的可能性最大;当采用湿烟气循环时或燃烧高硫分煤种时,磨煤机内均会发生严重的低温腐蚀;此外,锅炉负荷的变化对磨煤机腐蚀特性影响很小。关键词:富氧燃烧;干/湿烟气循环;热力特性;气体辐射;酸露点;低温腐蚀AbstractOxy-fuelcombustiontechnologyisanewgenerationofcleancoalpowergenerationtechnology,whichfluegasrecirculationsystemincludingdry,wettwotypes.Themaindifferenceiswhetherthepartfluegasoftheboilerexhaustafterdryingprocessisthenfedintothefurnacethroughtherecirculationsystem,twotypesoffluegascirculationeachhaveadvantagesanddisadvantages.Basedonoxy-fuelcombustionboiler,thispaperattemptstoresearchtheeffectsofdry/wetfluegasrecirculationmodeonthermodynamiccharacteristicsandsafty,whichisimportantforitslaterpracticalengineeringpurposes.Takea600MWpulverizedcoalboilerasanexample,thethermalanalysisofcoalunderdry/wetcycleofoxy-fuelmodesweredone,andtheresultswerecomparedwiththatunderaircombustion.Basedonenergybalance,theboilerwasredesigned.Theemissivitiesfortri-atomgaseshavealreadybeencalculatedbytheimprovedmodelofgasmixturesoverlappingbandandthebenchmarkmodelsunderdry/wetcycleofoxy-fuelmodes.Basedonfluegascomponents,effectofrecirculationmodeonaciddewpointoffluegaswasdiscussedforthefirsttime.Againstexistingproblemofcoalmilllow-temperaturecorrosionintheconventionalboiler,thepapertriedtostudythecorrosioncharacteristicsofcoalmillatoxy-fuelcombustionmode.Fluegascomponentsaresensitivetodesulfurizationanddehydrationatrecirculationmodesunderoxy-fuelcombustion.Comparedwithdrycyclemode,theresultofhigherboilerefficiencyandless
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