苯并恶唑类金属离子探针及金催化的氧化加成反应机理的研究-study on the mechanism of benzoxazole metal ion probe and gold-catalyzed oxidative addition reaction.docxVIP

目录第一章绪论.........................................................11.1概述...................................................................................................................................11.2荧光定义及产生机理.......................................................................................................21.2.1共轭π键体系41.2.2刚性平面结构.........................................................................................................41.2.3取代基的影响.........................................................................................................51.3荧光分子识别....................................................................................................................51.4荧光分子探针识别原理....................................................................................................71.5苯并噁唑为荧光团的冠醚的分子识别研究进展...........................................................141.5.1基于冠醚的分子识别............................................................................................141.5.2基于杂环冠醚的分子识别....................................................................................171.5.3苯并噁唑荧光冠醚的研究进展............................................................................191.6论文研究的主要内容......................................................................................................19第二章苯并噁唑为荧光团的二苯并18-冠-6醚分子识别研究..............212.1分子设计..........................................................................................................................212.2合成路线..........................................................................................................................212.3实验部分..........................................................................................................................212.3.1原料与仪器...........................................................................................................212.3.2二(4’,4’’-甲酰基)-二苯并18-冠-6(BCD-18-C-6)醚的合成222.3.32-甲基苯并噁唑的季膦盐制备.....................................................................