苯基脲类除草剂激发态动力学及光化学行为分析-analysis of excited state kinetics and photochemical behavior of phenylurea herbicides.docxVIP

5.3非草隆的紫外光谱探究................................................................................................495.4非草隆的共振拉曼光谱研究........................................................................................525.5基态S0和激发态S1的CASSCF计算575.6灭草隆与非草隆的共振拉曼光谱比对........................................................................595.7讨论与总结....................................................................................................................615.8参考文献........................................................................................................................63第六章二苯甲酮引发灭草隆光降解机理研究.........................................................................646.1前言................................................................................................................................646.2紫外光谱的获取............................................................................................................646.3二苯甲酮瞬态吸收光谱的获取....................................................................................656.4激发三重态的二苯甲酮和灭草隆反应的瞬态吸收光谱获取....................................676.5理论依据........................................................................................................................686.6结论分析和机理讨论....................................................................................................686.7讨论与总结....................................................................................................................696.8参考文献........................................................................................................................70硕士期间发表的论文...........................................................................................................71致谢.....................................................................................................................................72V中文摘要苯基脲类除草剂能抑制植物生长的活性，广泛应用于不同农作物芽前、苗后的阔叶与一年生杂草的控制，该类化合物化学性质稳定，且能长久的存在于环境中，造成土壤、地表水和地下水等污染，并可能对人有致癌作用。近几十年以来，科学家对苯基脲类除草剂在环境中的降解途径的探讨从未间断，但对其光物