固体酸催化fc酰基化反应脱除焦化苯中噻吩的研究-study on removal of thiophene from coking benzene by solid acid catalyzed fc acylation reaction.docxVIP

ABSTRACTChina is rich in coal，a great quantity of coking benzene would be obtained during the processes of coking coal. Coking benzene is an important industrial rawmaterial which is often used as fine chemical intermediate. Benzene as one of the main component ，which is widely used in chemical indus町， can be obtained by refining coking benzene. However，thiophene mixed in the coking benzene(mass fraction 0.2%-1.6%) can poison the catalyst and pollute the atmosphere during 由e reaction. 80 we have to remove thiophene from coking benzene ，if we want to obtain电 higher quantity benzene.80me removal methods of thiophene 仕om coking benzene were described in this paper. Friedel-Crafts acylation reaction is one of them，during which thiophene is converted into 2-acetyl thiophene which is valuable and widely used onpharmaceutical industry. This method makes it easy to separate benzene and thiophene by the way of widening the boiling point difference of those two ωmponents.Solid acids may be promising candidates to replace homogeneous acid cata1ysts(such as AICh ，BF3，H2804，etc.) which pose considerable problems such as toxicity， potential danger in handling，disposal problems due to large amount of acidic，eft1uen邸， and difficulties in product isolation. In this paper，several solid acids were tested among which Mont县10 h附加 highest conversion and selectivity. And then，，we tested the life of MontKI0 catalyst using the Catalytic Evaluation Device. The results show that the life and regeneration of Mont-Kl 0 are acceptable... At the end of this paper，the surface acidity of MontKI0 and Mont-KI0-supported ZnCh catalysts were characterized by F下IR technique ，and the mechanism of catalytic reaction is analyzed.Key words: Coking Benzene Thiophene 2-Acetylthiophene Mont-KI0 F丁IR Friedel-Crafts ReactionH 录目录前言……，…...………·……..… 1第一章文献综述....…..…..…川……...……….…… 21.1 研究历程及现状，……… 21.2 焦化苯脱硫技术简介…………...… 31.2.1 物理脱硫方法……………… 31.2.2 化学脱硫方法……………