煤氧化过程co产生机理及安全指标分析-analysis of co production mechanism and safety index in coal oxidation process.docx

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2018-07-27 发布于上海
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煤氧化过程co产生机理及安全指标分析-analysis of co production mechanism and safety index in coal oxidation process.docx

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煤氧化过程co产生机理及安全指标分析-analysis of co production mechanism and safety index in coal oxidation process

超限事故控制中进行了成功应用，保证了工作面的安全顺利启封。关键词：煤氧化、煤自燃、CO、积聚规律、安全指标研究类型：应用基础Subject:StudyontheProductionMechanismandSafetyIndexofCOintheProcessofCoalOxidationSpecialty:SafetyTechnologyandEngineeringName:ZhaiXiaowei（Signature）Instructor:DengJun（Signature）ABSTRACTMostofthecoalseamsbelongtoeasilyspontaneouscombustionandspontaneouscombustioncoalseamsinourcountry.Thecourseofnormalmininginhigh-yieldandhigh-efficiencymines,COisoftenaccumulatedinthereturncornerofface,becauseofhigh-miningintensity,easilyoxidationofcoalseamsandsoon.Coalspontaneouscombustionpredictionisdisturbedandmineproductionsafetyisaffected.ProductionmechanismofCO,andruleofaccumulationandcontrolarealwayskeyscientificproblemsofminespontaneouscombustionhazardprevention.ThemaincoalseamofLingwuminingareaischosenastheresearchsubjectinthepaper,microdynamicsofCOproduction,accumulationrule,safetyindex,preventionandcontrolmethodarestudied.ItprovidesthebasisfortheearlypredictionofthecoalspontaneouscombustionandCOoverrunmanagementingoaf.TakingmaincoalseamsamplesofLingwuminingarea,throughtheultimateanalysisandinfraredspectrum,coalmolecularstructurecontainingthemainactivegrouptypeisobtained.Basisonthequantumchemicaldensityfunctional,Gaussian-03WsoftwarewasemployedtosimulatethedynamicprocessofCOdesorptionofthemainactivegroupofcoal,andthreestepsofCOproducingintheprocessofcoaloxidationareobtainedaccordingtothesimulationtheoreticalanalysis.Usingthecoalspontanepouscombustiontemperatureprogrammedexperimentequipment,theCOgenerationruleunderdifferentoxygenconcentrationarediscoveredbytestingthecoalsampleatoxygenconcentrationof4%,8%,12%,14%,18%and21%.ThequantificationallyfunctionalrelationshipbetweenthetemperatureatlowlevelandCOgenerationwereestablished.ThethreeprocessesoftheCOgenerationwerefound.ThegenerationofCOwasinfluencedbybothoftemperatureandO2concentrationineachprocess.Thepropertyparametersandlimitparametersintheprocessofcoalspontanepouscombustionaregotbythecoalspontanepouscombustionexperimentequipment.Itprovidesthebasisforanalyzingthe