酶促酚类化合物聚合及其对纺织品功能改性和染色-enzymatic polymerization of phenolic compounds and their functional modification and dyeing of textiles.docx

酶促酚类化合物聚合及其对纺织品的功能改性和染色中文摘要Dye1和Dye2染色锦纶织物抗氧化性分别为98.50%和89.78%。合成的偶氮类染料可以作为功能染料应用于织物的一浴法染色及抗紫外、抗氧化性整理。通过―原位‖染色和改性技术，在酪氨酸酶作用下制备绿原酸、没食子酸和咖啡酸改性甲壳胺纤维，实现纤维具有抗氧化、消臭性能和着色，改善了纤维的耐酸碱性。红外谱图表明，改性剂分子与甲壳胺纤维之间为共价键结合。改性纤维对ABTS和DPPH自由基的抗氧化性均增强，对ABTS自由基的捕捉能力能达到接近100%；对氨气的消臭能力有所提高。绿原酸、没食子酸和咖啡酸改性纤维的颜色分别呈褐色、灰紫色和咖啡色。咖啡酸改性纤维在1%醋酸溶液中溶解速度变慢。绿原酸和没食子酸改性纤维溶解时，先是快速溶胀，之后慢慢溶解，并导致醋酸溶液粘度增加。且溶液粘度随改性时底物浓度、酶用量、改性时间的增加而增加。SEM发现经0.1MNaOH溶液碱处理后，绿原酸改性纤维表面变粗糙，没食子酸改性纤维表面裂缝更加密集和明显；其失重率分别在17%和14%左右，且失重率几乎不随碱处理温度而改变。关键词：多酚化合物;染色;改性;复合功能;氧化还原酶;聚合作者：孙莎莎指导老师：唐人成英文摘要酶促酚类化合物聚合及其对纺织品的功能改性和染色Enzyme-catalyzedPolymerizationofPhenolsandItsColorationandMultifunctionalModificationofFabricsAbstractTextiledyeingandfinishingisacriticalprocesstoproducenovel,topgrade,functionalandhighaddedvaluetextiles,andtoenhancetheinternationalcompetitivenessofthetextileindustry.ThescaleofthedyeingandfinishingindustryinChinaishuge,butthenegativeimpacttoresourcesandenvironmentcausedbyhighenergyconsumption,highemissionandhighpollutioninthedyeingandfinishingprocesscannotbeignored.Inordertoenhancethecorecompetitiveness,itisaninevitabletrendtodevelopnewecologicaldyeingandfinishingtechnology,tostrengthenthecombinationoftraditionalprintinganddyeingprocessingwithmodernbiotechnology,andtoshortentheexistingprocess.Basedonthemechanismofphenolsoxidationpolymerizationwithlaccaseandtyrosinase,theinsituenzymaticallypreparedpolymersforcolorationtechnology,andenzyme-catalyzedpolymerizationandthenadsorptionforcolorationtechnologywereusedtotextiledyeingandfinishing.Thedyedtextileobtainedcolorationwithasingleorcompositefunctionalities,suchashydrophilic,UV-protective,antioxidantordeodorizingperformance.Furthermore,thedissolubilitiesofthechitosanfibersmodifiedwithinsitutechnologyinaceticacidandalkaliwereinvestigated.Twoazofunctionaldyesderivedfrom3-methyl-2-benzothiazolinonehydrazone(MBTH)usingphenoliccompoundsweresynthesizedbyenzymaticsynthesis.Thepurposeofthisprojectwastoachieveecologicaldyeingandfunctionalfinishingofthenaturalfunctionalfinishingagentinoneste