纳米铁氧体磁性材料的物性分析与多孔有序氧化铝模板的制备-physical property analysis of nano ferrite magnetic materials and preparation of porous ordered alumina template.docxVIP
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纳米铁氧体磁性材料的物性分析与多孔有序氧化铝模板的制备-physical property analysis of nano ferrite magnetic materials and preparation of porous ordered alumina template
waspwaistandhighcoercivity,andthesampletakeonrepresentativeferrousmagneticproperty;withthetemperatureincreasing,saturationmagnetizationofsamplesincreaseslightlyandcoercivitydecrease,whichverybenefitstotheapplicationofstrontiumferriteinhigh-densitymagneticrecordingmaterials;theaveragegrainsizeofthehexagonalstrontiumferritesynthesizedbyannealingat1100℃for5hisabout100~150nm.ThephysicalpropertiesstudyofsoftferriteNano-crystalNi-ZnferriteswithdopingNiwerepreparedbyceramictechnique,sinteringat900℃for2h,andtheinfluencesofdopingNionthephysicalpropertiesofnano-crystalNi-Znferritewerestudiedalso.Theas-synthesizedsampleswerecharacterizedbyXRD、IR、SEMandVSM.Theresultsshowthat:theas-synthesizedNi-Znferritetakeonspinelstructure;Theabsorptionpeakaround577.76cm-1and418.86cm-1isthecharacteristicstretchingvibrationofoctahedronandtetrahedroninNi-Znferrite,furthermorewhenx=0.6,thecharacteristicabsorptionpeakisstrongerthanthatwhenx=0.4;magnetizationcurvesofsamplestakeonthin,thesaturationmagnetizationishigh,accordingwiththatofbulkmaterials;theas-preparedNi-Znferritenano-particlestakeonquasi-sphericaltype,thegrainsizeisabout80~100nm,andthesizeofparticlesisgenerallyuniform,whichisverydifferentfromtheamorphousnano-powderspreparedbymajorityofotherscholarsusingothermeanscalciningatabouve1000℃.ThepreparationoforderedporousaluminatemplateAccordingtotwostepelectrochemicalanodizationmethod,orderedporousaluminamembranesofhighlyregularstructurewerepreparedonthesurfaceofhighpurityaluminum.Theholesofas-preparedaluminumoxidemembranesdistributeveryregularly.Theholesarrangeparallel,theirdiameteranddensityarerespectively40nmand5×1010个/cm2,theaperturearrangedenselyintermsofhexagon,thecenterdistanceamongholesisabout60nm,theaxesofholesareverticaltothetheirsurface.Atlast,theformationmechanismoforderedporousaluminatemplateisalsoinvestigated.Keywords:nano-crystal;strontiumferrite;nickelzincferrite;sol-gelmethod;ceramictechnique;aluminatemplate独创性声明本人,明.1!的4(崎l:(牟λa导描导F.!町的研兜L悴且.离的顿11(堕..砸锅止..lttlt咿崎JII...L;(,手H
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