双亲性纳米tio2复合体的制备及其在聚偏氟乙烯pvdf超滤膜中的应用研究-preparation of amphiphilic nano - tio _ 2 composite and its application in pvdf ultrafiltration membrane.docxVIP

ABSTRACTPolyvinylidenefluoride(PVDF)usedfordevelopingultrafiltrationmembraneisanoptimalmaterialwithgoodwithstandvoltagecharacteristicsandcombinationproperty.OnthebaseofstudyofmodifiedPVDFultrafiltrationmembraneathomeandabroad,thehybridPVDFultrafiltrationmembranewiththepropertyofhighflux,resistcompression,foulingresistantwaspreparedthroughintroducingthemodifierofamphipathicnano-TiO2complex,whichcanimprovethepropertyofthehydrophilicityandcompactibilityofPVDFultrafiltrationmembrane,synthesizedaccordingtotheprincipleofmoleculardesign.Meanwhile,themechanismoffilm-formingandmodifyingwasdiscussed.Accordingtotheprincipleofmoleculardesign,theamphipathicnano-TiO2complexwasdesigned,withthenano-TiO2asitscore,silanecouplingagentKH-570asitshydrophobicchain,andAAandMMAcopolymerasitshydrophilicsegment.Theoptimalparametersofthecomplexwereasfollows:KH-5703wt.%(Relativetotheweightofnano-TiO2);AAandMMA60wt.%(TheratioofmonomerAAandMMAwaskeptbetween40%and50%);initiator0.08wt.%;monomerandinitiatoraddeddropbydrop;reactiontemperature80℃.Undertheseconditions,thegraftingrateofmonomercouldreach80%andthecomplexshowedgoodhydrophilicproperties.Themoldingprocesswasstudied.itwasdiscoveredthatthehydrophilicity,compatibilityandanti-foulingofthecomplexmembranewassignificantlyimprovedandmembranefluxcouldachieve90mL.cm-2.h-1whenPVDFwas20wt.%,PVP3wt.%,amphipathicnano-TiO2particles4wt.%,purewaterusedascoagulationsolutionandgelationtemperature20~25℃.Themodifyingmechanismofamphiphilicnano-TiO2complexwasstudiedandamodifyingphysicalmodelwaspresented.Themodifiednanoparticles,becauseofthehydrophobicchaininthesurface,canstablydisperseinthesurfaceandtheinsideofPVDFmembrane.Anislandstructurewasformedbyparticlesdecentralizinginthemembranetoenhancethemembranecompaction;whilethoseparticlesdispersinginVthesurfaceofmembranecanincreasethethickdegreeofthemembranesurfaceandintensifythehydrophilicpropertiesofmembrane.Surfacesegregationandenrichmentofthepolymerchainsgraftedinthesurfaceoftheparticleoccurredduringthegelproces