石英坩埚强结合致密涂层的设计与分析-design and analysis of dense coating for shi ying crucible.docxVIP

ABSTRACTInrecentyears,solarenergyhasreceivedextensiveattentionandbeenhailedasastrategicalternativeenergysourcesbecauseofitsabundance,wideradiation,safetyandnon-pollution,etc..Polycrystallinesiliconbecomesthemainrawmaterialofphotovoltaicmarketwithadvantagesoflowercost,simplerpreparationprocessandrelativelyhigherconversionefficiency.Themostcommonmethodofpreparationduringindustrialproductionisthedirectionalsolidificationwhichrealizespurificationofpolycrystallinesiliconthroughsegregationcoefficientsofimpurities.Thedirectionalsolidificationisperformedinaquartzcrucibleduetoitsrelativeavailabilityinhighpurityandhighmeltingpoint.Areactionbetweensilicaandliquidsiliconoccurswhenthetemperatureisclosetoorexceedsthemeltingpointofsilicon,leadingtoadhension.Consequently,intrinsicimpuritiesofcrucibleespeciallymetalimpuritieswhicharefatalcontaminationstoinfluencethequalityofsiliconevenattheppmandppbrangewilldiffuseintosiliconingotthroughthejuncture.Themajorsolutiontotheseproblemsencounteredintheprocessistoselectamaterialwithhightemperatureresistance,highchemicalstabilityandnoinfluenceonqualityofsiliconasanisolationlayerbetweeningotandcrucible.Si3N4meetstheserequirementscompletelyasanemergingmaterialwithhigh-performance.However,thephenomenonthatcoatingshedsfromcrucibleduringthedirectionalsolidificationseriouslyaffectsthequalityofsilicon.Thispaperaimedatimprovingthebindingstrengthbyco-sinteringofcoatingandgreensubstrate,introducingnanosilica,H3BO3ormixtureintoSi3N4slurryandadjustingthecontentsofthecomponents.Theexperimentalresultsindicatedthat:PVAandPVPsolutionhadbetterdispersionofSi3N4powdersandhadanimprovementforthestabilityofslurrycomparedwithwaterasdispersionmedium.Slurrieswith3wt%PVAand7wt%PVPasdispersionmedia,30wt%、35wt%Si3N4,respectively,wereselectedasthebaseslurries.Comparedwiththesinteredone,theunsinteredsilicasubstratewasmorelikelytobepermeatedbySi3N4slurry.AfterpretreatmentSi3N4waspartlyoxidatedtocristobalite,andthenthiscrystaltendedtobeamorphousaftertreatmentat1500oCinArat