湿气水稳定金属-有机框架材料合成及应用-synthesis and application of metal-organic frame materials stabilized by moisture and water.docxVIP

本论文所用配体的名称及缩写中文名称英文名称缩写名结构式4,4’-二(膦酸乙酯)联苯4,4-biphenyldiphosphonatebis(monoethylester)H2L(a)1,4-苯二甲酸1,4-BenzenedicarboxylicacidH2BDC(b)1,3,5-苯三甲酸1,3,5-BenzenetricarboxylicacidH3BTC(c)1,3,5-三咪唑基苯1,3,5-tri(1H-imidazol-1-yl)benzeneTIB(d)二(1-咪唑基)甲烷bis(imidazol-1-yl)methaneBIM(e)III目录摘要..............................................................................................................................IAbstract.......................................................................................................................II第一章前言..............................................................................................................11.1金属有机框架(Metal-organicframewoks)概述11.1.1MOFs材料的结构特征11.1.2MOFs材料的设计及合成方法21.2湿气/水稳定的MOFs材料的研究意义31.2.1湿气/水稳定的MOFs材料合成思路31.2.2湿气/水稳定的MOFs材料功能应用31.3本论文的选题依据..................................................................................................4第二章实验部分.....................................................................................................52.1实验试剂.................................................................................................................52.2实验仪器.................................................................................................................52.3有机配体的合成.....................................................................................................64.5小结.......................................................................................................................39参考文献......................................................................................................................40硕士期间已发表的研究论文......................................................................................50致谢........................................................................................................................51VI第一章前言金属有机框架(Metal-organicframewoks,简称MOFs)又称多孔配位聚合物，是指金属离子或金属簇与有机配体通过分子自组装形成具有周期性无限网络结构的晶态材料。由于MOFs具有比表面积高、孔结构修饰的多样性和结构可调控性等特点，在气体吸附与分离，催化传感，分子识别和药物缓释等领域具有广泛