双组份阻燃脲醛树脂胶研制及应用-development and application of two-component flame retardant urea-formaldehyde resin adhesive.docxVIP

合强度。在实验范围内，当阻燃剂添加量为8%，固化剂氯化铵为0.2%，此时阻燃脲醛树脂胶粘剂的胶合强度最高为1.31MPa，浸渍剥离合格率100%，均达到国家标准GB/T9846.3-2004《胶合板普通胶合板通用技术条件》的II类（≥0.7MPa）要求。（3）阻燃性能研究表明：阻燃脲醛树脂胶粘剂具有良好的阻燃能力。通过差热重量分析（TG）和电镜扫描（SEM）方式评价阻燃机理，发现阻燃脲醛树脂胶粘剂能显著降低木材热解的失重速度，使热解失重过程延长；同时降低木材的热解起始温度，使热解途径向着有利于生成炭和不燃物质方向转变，阻燃剂同时在凝聚相和气相起到了阻燃作用，阻燃效果良好，显现出对木材阻燃保护的功能。本文还研究了阻燃脲醛树脂胶粘剂用于开发阻燃实木复合地板及其制备技术，重点探讨了阻燃实木复合地板阻燃性能和甲醛释放量，得出结论如下：（1）甲醛释放量研究表明：按照国家标准GBl8580-2001《室内装饰装修材料人造板及其制品中甲醛释放限量》和GB/T17659-1999《人造板及饰面人造板理化性能试验方法标准》检测阻燃实木复合地板的甲醛释放量为0.2mg/L，达到国家E0级标准（≤0.5mg/L）。（2）阻燃性能研究表明：表面阻燃层具有显著抵挡外部热源向内辐射的能力，对实木复合地板具有良好的阻燃防护作用。按照GB20286-2006《公共场所阻燃制品及组件燃烧性能要求和标识》方法检测其燃烧等级为B1级。所有的试验结果表明阻燃脲醛树脂胶粘剂制备技术满足工业化V生产要求，实际应用性能良好，具有工业化生产可行性。关键字：新型复合磷-氮协同阻燃剂，阻燃脲醛树脂胶粘剂，胶合性能，阻燃性能VISYNTHESISANDAPPLICATIONOFTWOCOMPONENTFLAMERETARDANTUREA-FORMALDEHYDERESINADHESIVEABSTRACTPlywoodhasbeenwidelyusedinupholstery,furnituremanufacturing,packagingandotherfields,whichisimportantforpeopleslife.Theweaknessofflammabilityofcommonplywoodhaslimiteditsapplicationsinmanyfields.Therefore,thestudyofflame-retardingplywoodhasimportantsignificanceinpractice.Therearesomeproblemsonthefireretardanttechnologyofplywood,1)theprocessofflameretardanthandlingiscomplicated,2)theflameretardanthasnegativeeffectonbondingpropertiesofresin,3)theflameretardingeffectiseasilydecreasedowingtotheflameretardantiseasilylost.Itwasoneofthefocusestoovercomeabove-mentionedproblemsandsimplifytheflameretardanttechnologyintheresearchfieldoftheflameretardantwoodmaterials.Inthispaper,firstly,thesynthesisconditionsofnovelsynergyflameretardantcontainingphosphorus-nitrogenwerediscussedandstudied.Onthebasicofit,theflameretardantUFresinadhesivewaspreparedbymodifiedUFresinadhesiveandflameretardantthroughmechanicalmixingsystem.Thephysicalandchemicalproperties,bondingpropertiesandflameretardantpropertiesofflameretardantUFresinadhesivewereemphaticallystudied,andthemainconclusionsaresummarizedasfollows:PhysicalandchemicalpropertiesresearchshowedthattheflameretardantUFresinadhesivehadgoodphysicalandchemicalproperties.Inthe