铈基scr催化剂对燃煤烟气汞催化氧化的实验与机理分析-experimental and mechanism analysis of cerium-based scr catalyst for catalytic oxidation of mercury in coal-fired flue gas.docxVIP

200-350℃温度范围内都维持约100%的汞氧化率，具有比较宽的温度窗口。CWT催化剂的质量百分比为CeO2:WO3:TiO2=0.5：0.5：1时对汞具有最高的氧化效果。烟气成份NO、O2对CWT催化剂上汞的氧化有明显的促进作用，而SO2仅有微弱的抑制作用，说明该催化剂的抗硫性能较好。CWT催化剂上汞的氧化对HCl的依赖性低。CWT催化剂上汞的氧化遵循Langmuir-Hinshelwood机制。关键词：燃煤烟气；汞；催化氧化；SCR催化剂ABSTRACTCoal-firedpowerplantsareanimportantsourceofanthropogenicmercuryemissionsintheatmosphere.Mercurytooxidizedmercury(Hg2+),particulatemercury(Hgp)andelementalmercury(Hg0)existsinthreeformsinwhichthefluegas.Oxidizedmercury,whichissolubleinwater,thewetdesulfurizationdeviceiseasytoremove;particulatemercurycanberemoveddustremovaldevice;hardesttodealwithiselementalmercury,becauseitdoesnotdissolveinwaterandvolatile,soitiseasytoemissionsofatmosphericpollution.SCRcatalystcancatalyzetheoxidationofelementalmercury,buttheSCRcatalystintoindustrialapplications,therearesomeproblems,suchasanarrowtemperaturewindow,lowspecificsurfacearea,suchassulfurresistanceispoor,requiringthedevelopmentofnewSCRcatalyst,canbemoreefficientachievesynergynitrogenoxidesandmercuryremoval.ThispaperintroducesoxygenstorageabilityofCeO2andlargespecificsurfaceareaSiO2,usingthesoil-gelsynthesisofanewCeO2/TiO2-SiO2(CTS)catalystandbenchinafixedbedexperiments,thecatalystwasstudiedinasimulatedfluegascatalyticoxidationofelementalmercuryconditions.Theresultsshowthatundersimulatedfluegasconditions,CTScatalystforelementalmercuryoxidationefficiencycanreachabout100%,intherangeof150-250℃havereachedaveryhighoxidationefficiency.CTSNOoxidationcatalystcanpromotemercury,whileSO2isinhibited.CTSmercuryoxidationcatalystfollowedEley-Ridealmechanism.Synthesizedusingthesoil-gelmethodCeO2-WO3(CW)catalystinafixedbedexperimentbench,thecatalystwasstudiedundersimulatedfluegasconditionsofcatalyticoxidationofelementalmercury.Theresultsshowthatonly84%N2,4%O2,12%CO2unfavorableconditionsofthefluegas,CWcatalystfortheoxidationrateofelementalmercuryisstillashighas70%,indicatingthatintheabsenceofchlorinecase,CWcatalystformercuryhasagoodoxidationresistance.NOoxidationcatalystonCWpromotetheroleofmercury,SO2significantlyin