微纳米结构复合型tio2光催化剂的制备及其光催化性能研究-preparation and photocatalytic properties of micro-nano structured tio _ 2 photocatalyst.docxVIP

Abstract As a semiconductor photocatalyst, considerable attention has been focused on TiO2 owing to its unique properties and promising applications, such as air purification, waste water treatment, self-cleanness, mist prevention, bacillus resistance and so on. However, it is still a great challenge to overcome the problems of low photocatalytic activity and low utilization of sunlight. In recent years, there is a rapid development of the improvement of TiO2 photocatalyst, including the compositing of semiconductor, the doping of the transition metal ions and the non-metallic ions, the depositing of the precious metals and the sensitizing of TiO2 surface. In this paper, have been focused on the combination of nanosized TiO2 and other semiconductors materials based on its disadvantages. Micro/nano-structures ZnO/TiO2 and CuO/TiO2 composites photocatalyst were prepared by the hydrolyzation method in the surface adsorption layer of the micron dimentional ZnO and CuO. And the photocatalytic activity of the composites was given as a detailed research. The main contents are as follows: Firstly, the reaction mechanisms, the research progresses and the applications of TiO2 photocatalysts were reviewed. Secondly, in order to keep light electron and hole prolonging and improve the photocatalytic activity, TiO2 was composited with ZnO which has the similar band-gap. Zn(Ac)2 and NaOH are used without further purification, the micron dimentional flower-shape and rod-shape ZnO microcrystallines were prepared through a facile wet synthesis. Additionally, the micro/nano ZnO/TiO2 composite photocatalyst was successfully synthesized by the surface adsorption layer reaction with these microcrystallines as the carriers. Thirdly, TiO2 was composited with CuO which has the narrower band-gap to broaden the light response range, separate electron-hole pairs, and improve the photocatalytic activity. In a typical preparation, CuSO4·5H2O, NaOH, and C6H12O6 were all commercially avail