Ca,Sr对AM80镁合金显微组织和高温蠕变性能影响.docVIP

Ca,Sr对AM80镁合金显微组织和高温蠕变性能影响 　　摘要:采用扫描电镜(SEM)、X射线衍射仪(XRD)和高温蠕变试验机等实验手段研究了碱土元素Ca,Sr对AM80镁合金显微组织和力学性能的影响.结果表明:在AM80合金中复合添加0.2%Sr和0.5%~2.5%Ca,Ca、Sr元素可逐步细化合金的铸态组织,Ca原子与Al原子优先结合在晶界处生成了高熔点相Al????2Ca,抑制了低熔点相β??Mg????17??Al????12??的形成.AM80合金在高温蠕变过程中,β??Mg????17??Al????12??相在晶界处存在连续析出和非连续析出2种形式.β??Mg????17??Al????12??相非连续析出并且垂直于晶界,造成合金蠕变性能较差.当在合金中复合添加Ca,Sr后,高熔点相Al????2Ca是主要的晶界强化相,替代低熔点的β??Mg????17??Al????12??相,从而减少β??Mg????17??Al????12??相的非连续析出,抑制了晶界滑动,改善了合金的高温蠕变性能.当Ca质量分数增加到2.5%时,合金的高温蠕变性能最优. 　　关键词:钙;锶;显微组织;AM80镁合金;蠕变性能 　　中图分类号:TG146.2文献标识码:A 　　MicrostructureandCreepPropertiesofCastingAM80Alloy 　　ContainingCaandSr 　　LILuo??xing????1,2?k??,LIANGGui??ping????1,2??,BAIXing????1,2??,LIUBo??3,LIUYang??sheng??3 　　(1.StateKeyLaboratoryofAdvancedDesignandManufactureforVehicleBody,HunanUniv,Changsha,Hunan 　　410082,China; 　　2.CollegeofMaterialsScienceandEngineering,HunanUniv,Changsha,Hunan410082,China; 　　3.AutomotiveEngineeringInstituteBodyTechnologyResearchDepartment,ChongqingChanganAutomobileCOLTD,Chongqing401120,China) 　　Abstract:TheeffectsofalkalineelementsCaandSradditionsonthemicrostructureandmechanicalpropertiesofAM80magnesiumalloywereinvestigatedbyusingscanningelectronmicroscopy(SEM),X??raydiffraction(XRD)andcreeppropertiestestingatelevatedtemperature.Theresultsshowthatthemicrostructuresoftheas-castalloysarerefinedbyadding0.2%Srand0.5%~2.5%Ca.Ahigh??meltingpointAl????2CaphasedispersedlyformedatthegrainboundariesintheAM80alloyduetotheprioritycombinationofCaandAl,thustheformationofβ??Mg????17??Al????12??phasewasreduced.ThemechanicalpropertiesofthealloyswerealsoimprovedduetotheexistenceoftheadditionofCaandSr.Theβ??Mg????17??Al????12??phasehadtwokindsofprecipitationforms,whichwerenon??continuousprecipitationandcontinuousprecipitationduringcreepprocess.Thenon??continuousβ??Mg????17??Al????12??phaseprecipitatedatthegrainboundariesandwasperpendiculartothegrainboundaries,decreasingthecreeppropertiesofAM80magnesiumalloy.Theelevatedtemperaturecreeppropertiesofthealloysweregrea