(La,R)(Fe,Mn,Si)13Hx合金及粉末粘结样品磁热性能的研究材料科学与工程专业论文.docxVIP

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(La,R)(Fe,Mn,Si)13Hx合金及粉末粘结样品磁热性能的研究材料科学与工程专业论文.docx

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(La,R)(Fe,Mn,Si)13Hx合金及粉末粘结样品磁热性能的研究材料科学与工程专业论文

内蒙古内蒙古师范大学硕士学位论文内蒙古内蒙古师范大学硕士学位论文 ABSTRACT La(Fe1-xSix)13 series compounds with NaZn13-type cubic structure are widely concerned because of their low raw material costs, non-toxic cinstituting, continuously adjustable Curie temperature (Tc) and good magnetocaloric effects (MCEs) compared with other magnetic refrigeration compounds, which is one of the most promising candidate for magnetic refrigerant. In this paper, the MCEs of hydrides and their bonded samples of La(Fe1-xSix)13 series compounds are investigated. The La0.9Ce0.1Fe11.7Si1.3H1.8 and La0.9Ce0.1Fe11.41Mn0.29Si1.3H1.8 alloys were prepared, and the two kinds of powder bonded samples of hydrides were obtained by bonding technology. The samples had the same major phase of NaZn13-type cubic structure before and after bonding, and there is a small amount of ?-Fe as impurity phase in their hydride and powder bonded samples. The two bonded samples show a very good compressive strength of 320 and 332 MPa, about 10% and 14% higher than that of bulk LaFe10.99Co0.91Si1.1B0.2 compound. By partial substitution of Mn for Fe, the Tc of bonded La0.9Ce0.1Fe11.7Si1.3H1.8 decreases remarkably from 325 to 279 K. The magnetic entropy change (?Sm) for bonded La0.9Ce0.1Fe11.7Si1.3H1.8 and La0.9Ce0.1Fe11.41Mn0.29Si1.3H1.8 slightly reduces compared with hydride alloys, but still maintains large values of 8.8 and 7.9 J/kgK. The two bonded samples exhibit the same adiabatic temperature change (?Tad) of about 2.6 K under a field change from 0 to 1.5 T. The bonded La0.9Ce0.1(Fe,Mn)11.7Si1.3 hydrides samples with good magnetocaloric effects and better mechanical properties are promising as high performance magnetic refrigerants materials. The alloys and powder bonded samples of La1-yCeyFe11.41Mn0.29Si1.3Hx (y = 0.0, 0.1, 0.2, 0.3, 0.4) and La0.9Ce0.1Fe11.7-zMnzSi1.3H1.8 (z = 0.27, 0.29, 0.31, 0.33, 0.35) were prepared by hydrogen absorption and bonding technology, respectively. When y?0.3, with increasing Ce content, the lattice c