(Nd,Ca)(Al,Ti)O3基微波陶瓷制备工艺参数和结构与性能的相互作用材料学专业论文.docxVIP

哈尔滨工业大学硕士学位论文 哈尔滨工业大学硕士学位论文 - - II - Abstract Recently, more attention has been paid to microwave dielectric ceramics due to its excellent microwave diectric properties, for example, high diectric constant, ultral low dielectric losses, and near zero temperature coeffcient of resonant frequency. As a medium dielectric constant microwave dielectric ceramics, (1-x)NdAlO3-xCaTiO3 has been used widely in wireless communication. In the present thesis, in addition to the dependence of microwave dielectric properties on the x of NACT based microwave dielectric properties, the relationship between the processing and microstructure and microwave dielectric properties of NACT ((1-x)NdAlO3-xCaTiO3) based microwave ceramics were investigated. Previous investigation shows that the microwave dielectric properties of NACT based microwave dielectrics are very sensitive to the processing, stoichiometry, and point defects. In the present thesis, we focus our study on the effect of preparation technique and processing parameter on the sintering density and microwave dielectric properties. It is necessary to fabricate NACT microwave ceramics with a εr42 dielectic constant, -12τf10ppm/℃temperature coeffcient of resonant frequency,and a 3000 loaded Q-value. Conventional solid state processing and two-step reaction synthesis of NACT have been used to fabricate undoped NACT microwave ceramics, but these two methods are both failed to fabricate ceramics with high performance due to the slow difussion processing among the atoms that results in the secondary phase. We successfully fabricated the undoped NATC based microwave dielectric ceramics using high energy ball-milling technique with εr=44, τf～-5ppm/℃, and a 3800 loaded Q. Among all the investigated NACT based ceramics with 0.66x0.74, a maximum loaded Q value (~3800) appears when x=0.70. The Q values can be improved further after annealing treatment. Keywords: (1-x)NdAlO3-xCaTiO3 ） microwave ceramics, Process, High energ