TIPS和NIPS法制备聚偏氟乙烯膜及其性能研究-化学工程专业论文.docxVIP

Abstr Abstract Shanghai Normal University Master of Chemical Engineering 万方数据 万方数据 membranes. The mechanism properties can also enhanced with proper amount of O-MWNTs. Last，on the basis of the previous two sections, C-TIPS were proposed to prepare PVDF/PFSA charged membranes. Effects of casting temperature and PFSA content on the morphologies, permeation performances, electro kinetic properties, crystalline form, and contact angles of the resultant PVDF membranes were investigated in detail. The results show that the all membranes have asymmetric structure with macro-voids in the cross sections. Much higher casting temperature leads to the formation of thicker top skin layer and thus a decrease in permeation flux. Adding PFSA in dope solutions can improve the surface hydrophilicity, porosity and apparent zeta potential (ζapp) in absolute value, and promote the permeation flux of the resultant PVDF membranes. The crystal forms of PVDF membranes are mainly β phase, and the crystallinity slightly increases with the increase of casting temperature. Keywords: Thermal induced phase separation method; non-solvent induce phase separation method; Composite thermally induced phase separation method; Multi-walled carbon nanotubes; Polyvinylidene fluoride IV 上海师范 上海师范大学硕士学位论文 目录 目录 摘要 .............................................................. I Abstract ........................................................ III 第 1 章 综述 ....................................................... 1 1.1 膜分离技术介绍.............................................. 1 1.1.1 膜的分类和分离特点 ..................................... 1 1.1.2 常见的膜材料及各自特点 ................................. 2 HYPERLINK \l _TOC_250008 PVDF、PFSA、CNTs 简介 3 HYPERLINK \l _TOC_250007 PVDF 简介 3 HYPERLINK \l _TOC_250006 PFSA 简介 4 HYPERLINK \l _TOC_250005 CNTs 及其功能化简介 4 HYPERLINK \l _TOC_250004 TIPS 法和 NIPS 法简介 6 HYPERLINK \l _TOC_250003 TIPS 法和 NIPS 法定义 6 HYPERLINK \l _TOC_250002 TIPS 法和 NIPS 法的优缺点 6 HYPERLINK \l _TOC_250001 TIPS 法和 N