微波消解ICPMS法对冬虫夏草不同部位5种重金属元素分布研究.docVIP

微波消解ICPMS法对冬虫夏草不同部位5种重金属元素分布研究 　　[摘要]应用微波消解ICPMS法测定了20批冬虫夏草中5种重金属铜（Cu）、铅（Pb）、砷（As）、镉（Cd）、汞（Hg）元素的残留量，并分析了5种重金属在冬虫夏草不同部位的含量。结果表明，在《中医药中药材重金属限量》ISO国际标准下，所有批次样品中Cu，Pb，Cd，Hg 4种重金属元素的残留量均符合要求，且该4种元素在子座中的含量均高于虫体中的含量；重金属As的超标率为8824%，样品中As主要集中于虫体部分，虫体中As的含量是子座的7～12倍。该研究阐明了冬虫夏草中5种重金属的分布规律，同时分析了现行冬虫夏草重金属砷限量标准所存在的问题，并提出了相关建议，希望能为冬虫夏草重金属砷的限量标准制定提供参考。 　　[关键词]冬虫夏草； 微波消解ICPMS； 重金属； 分布 　　Study on distribution of five heavy metal elements in different parts of 　　Cordyceps sinensis by microwave digestion ICPMS 　　ZHOU Li1，2， HAO Qingxiu2， WANG Sheng2， YANG Quan1， KANG Chuanzhi2， YANG Wanzhen2， GUO Lanping1，2* 　　（1College of Traditional Chinese Medicine， Guangdong Pharmaceutical University， Guangzhou 510006， China； 　　2State Key Laboratory Breeding Base of Daodi Herbs， National Resource Center for Chinese Materia Medica， 　　China Academy of Chinese Medical Sciences， Beijing 100700， China） 　　[Abstract]The contents of five heavy metals （Cu， Pb， As， Cd， Hg） in 17 batches of Cordyceps sinensis were determined by microwave digestionICPMS， and their distribution in C sinensis were analyzed The results showed that the contents of Cu， Pb， Cd and Hg in all batches were in accordance with the international standards of Chinese MedicineChinese Herbal Medicine Heavy Metal Limit， with their contents in the stroma higher than that in the caterpillar body， and the excess rate of As， which mainly concentrated in the caterpillar body part of C sinensis， was 8824%， as the content of As in the caterpillar body was 7 to 12 fold of that in the stroma In this study， the distribution of five heavy metals in C sinensis was clarified， and the existing problems of arsenic limit of heavy metal in C sinensis were analyzed， and some suggestions were put forward It is hoped that the reference standard can be provided for the limited standard of arsenic in C sinensis. 　　[Key words]Cordyceps sinensis； microwave digestionICPMS； heavy metals； distribution 　　冬?x夏草系麦角菌科真菌冬虫夏草菌Cordyceps sinensis （BerK） Sacc 寄生在蝙