竹粉淀粉复合发泡材料的制备及其性能分析-preparation and performance analysis of bamboo powder starch composite foaming material.docxVIP

万方数据 万方数据 适；（5）随着发泡剂含量的增加，材料的吸水率先增加后减少，AC/ZnO 发泡剂含量为 3%时材料的吸水率达到最大值，分别为 71.8%；（6）当 甘油/DOP 含量为淀粉质量的 30%，植物纤维含量 20%，发泡剂含量 为 3%，挤出温度为 140℃，挤出压力为 70MPa，注塑速率为 11g.s-1 时，制品泡孔大小适中，数量较多，且分布均匀。 关键词：淀粉，竹粉，发泡，回弹率，泡孔形态 II ABSTRACT Starch-based foam composite is degradable by being prepared with starch as matrix, modified with additives as plasticizer, compatilizer, foamer and processed by extrusion, injection or baking foaming. On the one hand, the starch-based foam composite has good biodegradation to replace non-biodegradable foamed plastic especially EPS, so it makes for relieving the problems of white pollution and oil shortage; On the other hand, it is helpful to improve the added value of starch and add agricultural economic benefits; However, there are some common problems of the starch-based foam composite, such as poor compatibility and water resistance, cells with uniform distribution and low expansion rate and rebound rate. Therefore, performance of starch-based foam composite is still not as good as EPS and limits its wide application in the market. If we can get breakthrough the above problems, it will bring hope for its application in the market. In the bamboo power/starch foam composites （ PFRSP ） were prepared with starch as matrix, strengthened by bamboo power, modified with additives as plasticizer, compatilizer, foamer and processed by injection foaming. Firstly, starch was plasticized by glycerol/DOP to explore the plasticizing mechanism; PVA was used to research interface mechanism of fiber/starch composite; The influence of glycerol/DOP、fiber、PVA content and temperature on the melt rheology was researched. Secondly, it was investigated that glycerol/DOP 、 bamboo power 、 foamer 、 PVA content and extrusion molding process parameters (extrusion temperature, extrusion pressure, extrusion frequency) effected in composites’ apparent density, expansion raterebound rate, degradability, melt rheology and cell expansion. The results showed that: (1)