聚苯胺蒙脱土导电复合材料制备与性能研究.docVIP

聚苯胺蒙脱土导电复合材料制备与性能研究 　　摘 要:采用电化学聚合法制备了插层聚苯胺钠基蒙脱土复合材料。探讨了复合材料前躯体插层苯胺-钠基蒙脱土的制备过程,采用X射线衍射(XRD)、扫描电镜(SEM)和电化学方法对复合材料的形貌结构和性能进行了表征。XRD结果表明,经苯胺插层后钠基蒙脱土的层间距明显增大,插层苯胺经电化学聚合后,其层间距仍比纯钠基蒙脱土层间距大,但小于苯胺插层的钠基蒙脱土。SEM照片表明,经电化学聚合后,钠基蒙脱土复合材料的致密程度高于未经电化学聚合的钠基蒙脱土的致密度。由插层聚苯胺-钠基蒙脱土复合材料修饰的电极对甲醇的电化学氧化和铁氰化钾的氧化还原具有优异的电催化性能。 　　关键词:聚苯胺;钠基蒙脱土;复合材料 　　中图分类号: O69文献标识码: A 　　Preparation and properties of polyaniline-montmorillonite conductive composite material 　　ZHOU Hai-hui 1,2, CHEN Juan1 , FU Chao-peng1 , CHEN Jin-hua1,2, KUANG Ya-fei1 　　(1 College of Chemistry and Chemical Engineering, Hunan University , Changsha , Hunan 410082 , China;2 State Key Laboratory of Chemo/Biosensing and Chemometrics, Hunan University , Changsha , Hunan 410082 , China) 　　 　　Abstract: Polyaniline-Na+-montmorillonite(PANI-Na+-MMT)composite material was synthesized by electrochemical polymerization method. Preparation process of aniline- Na+-montmorillonite precursor was discussed in detail. X-ray diffraction (XRD), scanning electron microscopy (SEM) and electrochemical method were used to characterize the composite. XRD result shows that the interlamellar space of Na+-MMT increases obviously after being intercalated by aniline. Moreover, the interlamellar space of Na+-MMT after electropolymerization is bigger than that of pure Na+-MMT, but smaller than that of aniline intercalated Na+-MMT. SEM image shows that the Na+-MMT composite material after electropolymerization becomes denser. The electrocatalytic properties of the PANI-Na+-MMT modified electrode for the electrochemical oxidation of methanol and redox of potassium ferricyanide are excellent. 　　Key words : polyaniline; Na+-montmorillonite; composite material 　　 　　掺杂态导电聚苯胺是一种新型的有机导电聚合物,其在电化学催化[1]、电化学超级电容器[2]、金属防护涂层等方面有着广泛的应用前景[3]。但由于导电态的掺杂聚苯胺具有强烈的分子间作用力和高刚性的分子链,使用传统方法难以对其进行加工,因而使得其应用开发受到一定限制[4]。聚苯胺的复合改性技术是一种提高其加工性能、获取多功能特性和拓宽其应用领域[5-6]的有效方法。聚苯胺蒙脱土(PANI-MMT)纳米复合材料的制备和性能研究已受到人们的关注[7-8]。Jinsoo使用过硫酸铵作为氧化剂,十二烷基苯磺酸作为掺杂剂和乳化剂制备了PANI-DBSA-MMT复合材料,同时对其电磁屏蔽效应和温度与电导