煅烧胶状黄铁矿净化水中铜离子的作用和机理-环境工程专业论文.docxVIP

Performance and mechanism of copper removal from wastewater by calcined colloidal pyrite ABSTRACT Colloidal pyrite, was collected from Xinqiao deposits in Tongling, Anhui. The structural evolution, magnetic susceptibility and arsenic content of colloidal pyrite were studied. The colloidal pyrite was heat-treated under N2 atmosphere and charaterized with X-ray powder diffraction (XRD), field emission scanning electron microscope (FE-SEM), magnetic susceptibility meter, and atomic fluorescence spectroscopy (AFS). Batch experiment was investigated on the physicochemical factors of Cu2+ removal from aqueous using calcined colloidal pyrite (CCPy) under inert atmosphere, and the factors included calcined temperature, initial solution pH, initial Cu2+ concentration, sorption time, sorption temperature and foreign ions. Besides, laboratory column tests were conducted to study and assess the potential of calcined colloidal pyrite (CCPy) as a low cost sorbent material to remove and recover copper (Cu) from aqueous solutions. The X Ray Fluorescence (XRF), X-ray diffraction (XRD), field emission scanning electron microscopy (FE-SEM) image, X-ray photoelectron spectroscopy (XPS) and High Resolution Transmission Electron Microscopy (HR—TEM) were used to characterize CCPy after sorption of Cu2+. The results indicated that: (1) phase transition behaviours of colloidal pyrite have occurred as it was firstly transformed into magnetite and monoclinic pyrrhotite, then hexagonal pyrrhotite, finally quartet pyrrhotite as well as the troilite when calcined under inert atmosphere. (2) colloidal pyrite calcined at 500-550°C was best for Cu2+ removal. Increasing pH was propitious to the copper removal. The metal sorption yields also increased with the increasing initial concentration and contact time, and reached to equilibrium at 24 h; the endothermic and spontaneous Cu2+ sorption process on CCPy fitted the second-order quation well, which could be well described by the Langmuir