对羟基苯甲酸酯类防腐剂在水中的光降解研究-市政工程专业论文.docxVIP

华中科技大学硕士 学位论 华 中 科 技 大 学 硕 士 学 位 论 文 II II 范围内增大而增大；（3）含有较多含氧官能团的富里酸级分对水体中对羟基苯甲酸 酯类化合物的光敏化有较大的影响，因 (3-10k)及 (30-100k)级分中含氧官能团及荧 光生色团的含量较高，能产生较多的3FA?，降解速率较快。（4）腐殖质在模拟太阳光 照射下产生三线态3HS?是对羟基苯甲酸酯类化合物敏化降解的主要原因，其降解通 过对羟基苯甲酸酯类化合物相关原子的电子转移到3HS?进行。 关键词：对羟基苯甲酸酯类化合物 光降解 铁(III)-柠檬酸盐 腐殖质 速率常数 III III Abstract The parabens have been widely used and defected in natural waters. As parabens cannot be completely eliminated by conventional wastewater treatment plants, they have been widely detected in surface waters. The occurrence of parabens in the aquatic environment has raised public concern over the potential suspected adverse ecological or human health effects. It has been reported that these compounds have weakly oestrogenic activity and reproductive toxicity. It is essential to develop effective techniques to remove these compounds. As Fe(III)、citric acid and humic substances are widely distributed in nature, this study is based on these two sysetms.The main content and results obtained were as following: The photodegradation of four parabens by Fe(III)-citrate system from aqueous solution was studied. Besides, the impact of pH value, various aqueous media and low-molecular-weight acid on the photosensitization of parabens were investigated. Results suggested: (1) the formation of HO? at different Fe(III)-to-cit molar ratios was analysed. The optimal Fe(III)-to-cit ratio was chosen for the elimination of parabens by Fe(III)-cit complexes. Fe(III)-cit-induced HO? formation rate increased with decreasing pH at the Fe(III)-to-cit ratio of 10:50 (10?6 M). Lower ratio such as 10: 150 and 10:500 led to different order for HO? formation. (2) the pH-dependent HO? production are governed by the stability of Fe(II)/Fe(II)-cit and amount of O2??. (3) The photodegradation efficiency decreased with increasing pH within the range of 5.0-8.0 at fixed Fe(III)-to-citrate ratio of 10:150 ?M and follow the order of pH 5.0 6.0 6.5 7.0 8.0. The photodegradation of parabens have been investigate