超临界二氧化碳中甲苯的选择性氧化反应研究-化学工艺专业论文.docxVIP

ABSTRACT ，Benzaldehyde is an important chemical intermediate ，and 批 W剧 used widely. However ，the application ofproducts was limited，because ofthe lower pur扰y and the lower yield. Supercritical f1uids could improve the reaction process，because of the higher selectivity，faster reaction rate，and products could be separated easily. ， 拙ηlerefore it w， studied widely，ωimprove the 衍aditional process，using the special properties of supercritical f1uids. To explore a new synthesis of 拙 ηlerefore it w process of oxidation oftoluene was studied in supercritical carbon dioxide. Firstly，we studied the solubility of toluene ，benzyl alcoho henzaldehyde ，and benzoic acid in supercritical carbon dioxide，with visual equilibrium devices.ηle resuhs showed that，the toluene has an high solubility of in supercritical carbon dioxide ，and ωlueneC02 system could form single ph脚， uoder the reaction condition. And the solubility of be阳yl alcohol，benzaldehyde ，and benzoic acid in supercritical carbon dioxide reduced with the polarity enhanced. So，the synthesis of benzaldehyde could be realized in higher selectivity，because of the di他rent solubility ofthe oxidation products. In addition， the phase behavior ofheterogeneous catalysts in toluene?supercritical carbon dioxide system was also explored. And the catalysts could be dispersed in supercritical carbon dioxide uni伽mly. Secondly，the e班ects of time，pressure ，temperature ，and molar ratio 00 the selectivity and conversion were investigated，in the reaction system without catalyst in supercritical carbon dioxide. And the appropriate reaction conditions were determined. In addition， contra剑 experiments were investigated in pure oxygen system and nitrogen system， in order to explore the advantages in supercritical carbon dioxide. The results showed that， the overoxidation could be inhibited ，and the total selectivity of benzyl alcoho benzaldehyde ，and benzoic acid was about 3 times than in the pure