多功能引发-调控剂的合成及其在活性自由基聚合中的应用研究-材料科学与工程专业论文.docxVIP

II II 中文摘要 多功能引发-调控剂的合成及其在活性自由基聚合中的应用研究 化率（＜ 50 %）下，聚合体系的调控性非常好，聚合是具有典型的“活性”/可控自 由基聚合特征的。但是在高转化率（＞ 50 %）下，虽然聚合物的相对分子质量随着 单体转化率线性增长，但是分子量分布比较宽（＞ 1.4），聚合体系的可控性有所下降。 通过核磁氢谱（1H NMR）和大分子质谱（MALDI-TOF MS）测试对所得的聚合物做 了表征。 最后，研究了既含有三硫代羰基结构又含有偶氮类引发剂结构的试剂（X6）在多 嵌段共聚物以及环状聚合物的合成中的应用。以X6作为引发剂和链转移剂，在60 oC 成功合成了苯乙烯（St）与丙烯酸甲酯（MA）的多嵌段共聚物以及丙烯酸正丁酯（nBA） 与丙烯酸叔丁酯（tBA）的多嵌段共聚物，而且在该体系中丙烯酸正丁酯（nBA）与 丙烯酸叔丁酯（tBA）的多嵌段共聚物的嵌段数达到了13段，在没有额外加入引发剂 的情况下，大大提高了多嵌段共聚物的合成效率，并且初步探索了其在环状聚合物合 成中的应用。 关键词： ICAR ATRP，MADIX/RAFT，乙酸乙烯酯，多嵌段共聚物，多功能 作 者：吴英 指导教师：朱健（教授） PAGE PAGE IV M ultifunctional initiator-mediator combos: synthesis and application in living radical polymerization Abstract Multifunctional initiator-mediator combos: synthesis and application in living radical polymerization Abstract In this thesis, three dual functional reagents which acted as initiator and mediator simultaneously were designed and synthesized. Then, the application of these reagents in corresponding controlled/“living” radical polymerization were studied. The current research provided an efficient way to simplify the polymerization components, which would evidently benefit for reducing possible side reaction caused by the complicated components as well as achieving precise control of the polymer structure. The detailed investigations were summarized as follows: Firstly, a dual functional reagent named N2 which containing both the thermal azo initiator group and bromine based ATRP initiator group was synthesized. The atom transfer radical polymerization (ATRP) of methyl methacrylate (MMA) was investigated by using N2 as both the initiator and reducing agent. The results showed that polymers with defined structures and controllable molecular weights as well as narrow molecular weight distributions were obtained. The polymerization of MMA using N2 as dual functional reagent has been proved as a typical living radical polymerization. Polymers with determined end group structure were obtained which was demonstrated by