掺杂改善MgB2超导体晶间连接性和磁通钉扎性能研究材料加工工程专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - ABSTRACT Since the discovery of superconductivity in MgB2 in 2001, the interface morphology and electric property have been studied in many types. However, as a promising candidate for high field magnet use, the critical current density of MgB2 is still insufficient. So the focus of the research is to find out a way of improving the grain connectivity and increasing pinning centers to improve the critical current density in high magnetic field. Since doping is a traditional way of improving MgB2 properties. the doping of Cu and Al were used in the experiments reported here. However, the doping mechanisms of Al and Cu are different. The mechanism of Cu doping is reacting with Mg to generate second phase MgCu2, which can improve the grain connectivity and form pinning centers to improve the critical current density in high magnetic field. However, the mechanism of Al doping is substitution of Mg in MgB2 crystal structure, which brought about crystal distortion that is an effective pinning centers. The grain connectivity has relationship with the fabrication process, so the fabrication of MgB2 powder and bulk were studied with different parameters. According to the fabrication of Cu addition MgB2 powder, by means of changing the ratio of Cu doping, sintering temperature, holding time, and surface area of stainless steel mesh, two sintering parameters with good intercrystalline connectivity were obtained, namely: Mg: B: Cu = 1.1:2:0.1, 600 °C +5h and 750 °C +2h, an additional 10% Mg increased the flow of molten Mg and made up the volatilization when sintering. According to the fabrication of Al addition to MgB2 powder, the different percents of Al and Mg were studied. The Al content causes dramatic increase in lattice distortion, and Mg content influences the phase composition. A series of experiments showed than a ratio of Mg: B: Al = 1:2:0.1, heat treated under argon (Ar) gas at 750°C+2h gave good parameters. In the fabrication