从磷石膏中提取稀土的实验研究-有色金属冶金专业论文.docxVIP

Experimental Study on Extracting Rare Earth Elements From Phosphogypsum Abstract Rare earth resource is a strategic economic resource around the world, the main existing state of the rare earth elements in the earth crust is mineral. Only about 10 species have industrial exploitation value though more than 20 species rare-earth minerals have been found in the nature, the most important species are: the rare mineral ore deposits (ce fluorine lanthanide fco3), la, industrial concentrate containing rare earth oxides about 60-70%, cepo4 alone, th3 (po4 )4 ,industry concentrate have rare earth approximately 60%, phosphorus ore concentrate of yttrium, rare earth industry with yttrium about 30%, ion adsorption type rare-earth ore, etc. Although china have rich rare resources, rare earth resources accounts for 26% plus in the world , with the exploitation and utilization of resources, rare earth resources have reduced continuously. It is necessary to find an economic and reasonable way to use and explore the rare earth resources. In this paper, the optimum process conditions of leaching rare earth elements from phosphogypsum and the experiment condition of extracting rare earth elements from the leaching solution were studied, which provided reference for the utilization of phosphorite ores which contain rare earth elements. the leaching experiment of phosphorite ores was investigated. The results indicated that the distribution proportions of ∑reo in phosphogypsum could come up to 95% by cycling leaching of phosphorite ores while the distribution proportions of ∑reo in solution could be increased by leaching and washing of phosphogypsum. The results showed that the optimum conditions of leaching process of phosphogypsum were that the ratio of liquid-solid in the first leaching stage was 2:1, the leaching temperature was 60℃,the leaching time was 3.5 h, the h2so4 dosage was 10%, the ratio of liquid-solid in the second leaching stage was 1:1, the leaching temperature was a