二嗪磷和吡虫啉缓释颗粒剂的制备及释放研究-化学工程专业论文.docxVIP

当改性剂在膨润土上的负载量超过 1.0 CEC 的时候，季铵盐阳离子的总量 超过了可交换的阳离子的总量，而二嗪磷药物分子与超过的那部分阳离子 竞争吸附到膨润土的表面，这就会导致二嗪磷不易吸附到有机改性的膨润 土上。降低了膨润土层间域的疏水性及其对二嗪磷分子的吸附能力，再增 加季铵盐的载量对二嗪磷的缓释作用的影响减小。当用相同量改性剂的时 候，改性剂的碳链越长，则二嗪磷的吸附越容易。 2、吡虫啉分子具有较强的极性，无论是短碳链有机膨润土还是长碳链 有机膨润土，暴露的硅氧烷表面相对于碳氢基团具有更强的吸附作用，延 长季铵盐改性剂的碳链长度增强了有机膨润土对吡虫啉的吸附系数，但是 降低了标碳化吸附系数。吡虫啉-海藻酸-有机膨润土颗粒剂的水中释放研究 表明，有机改性膨润土和海藻酸能够使突释效应降低，使颗粒剂在水中能 够缓慢释放出吡虫啉，延缓吡虫啉的释放速率。 关键词：二嗪磷 吡虫啉 有机膨润土 海藻酸钠 吸附 释放 STUDY ON PREPARATION AND RELEASE OF DIAZINON AND IMIDACLOPRID SUSTAINED RELEASE GRANULES ABSTRACT It is an effective strategy that people use controlled-released formulations to improve the efficiency of pesticides and reduce the environmental pollution. the work use modifier to prepare a series of organic bentonite, and characterizes the structural characterization of organic bentonite, studies the adsorption properties of organic bentonite to diazinon in equilibrium and non equilibrium state , analyzes the adsorption mechanism and the influence factors of diazinon on organic bentonite. Prepare the sustained-release granules of diazinon, and analyzes the release behavior of diazinon from granules in water, researches the structural characterization of organic bentonite to the influence mechanism of release kinetics of diazinon from organic bentonite. At the same time, the work, as comparison, also utilizes the DTMAC and HTMAC as modification to prepare a series of organic bentonite, and researches the isothermal adsorption of imidacloprid, analyzes the adsorption mechanism and the influence factors of imidacloprid on organic bentonite. In addition, add sodium alginate to imidacloprid - organic bentonite to prepare imidacloprid - alginate organic bentonite granules and characterizes the granules, analyzes the water swelling of imidacloprid - alginate organic bentonite granule. Simultaneously the paper analyzes the release behavior of imidacloprid from granules in water, researches the structural characterization of organic bentonite to the influence me