催化臭氧氧化—BAC用于高氨氮重污染水处理的中试研究市政工程专业论文.docx

Abstract Serious source water pollution in China makes conventional drinking water treatment ineffective. More and more water plants have adopted advanced treatment processes, among which the most popular one is ozonation – biological activated carbon (BAC). However, poisonous and harmful trace refractory organics are found constantly. Removing such matters by ozone alone is limited so that catalysts are introduced into this system to improve removal efficiency. Further, different catalysts have various mechanisms. Therefore, three-stage catalytic ozonation process coupled with three kinds of catalysts is proposed to removal refractory organics and control bromated. In this study, aiming at river-net source water with high ammonia nitrogen and high organics in south China, 120m3/d pilot study of three-stage catalytic ozonation process was proceeded for ten months. To research and select reasonable processes, water treatment units ahead could be switched or surpassed, which supplied three kinds of influent for advanced treatment. Result showed that effluent water qualities met the national standards all around the year by BAF, coagulation-precipitation, filter and three-stage catalytic ozonation-BAC processes treated. Even if water temperature was 5℃～8℃ in winter, effluent oxygen consumption 2.6mg/L, ammonia nitrogen 0.5mg/L, UV254 0.03cm-1, Mn 0.5mg/L, turbidity 0.2NTU, bromated 5μg/L, THMsFP 45μg/L. Meanwhile, influence of ozone stage and BAC stage was analysed, including temperature and water quality controlled by nature condition and a large munber of artificial controllable factors, such as ozone dosage, feeding methods, ozone contacting time, catalysts performance, EBCT, flow direction, carbon lay height and so on. It was suggested that less ozone dosage, one point feeding, shorter contacting time and no catalysts adding were benefit for ammonia nitrogen control; Comparing to zone feeding methods, contacting time and whether catalysts adding or not, oxy