拉曼光谱原位在线检测毛细管反应器中亚临界水水解甲氯化碳--研究.pdf

Raman、GC、GC—MSandIC．Theresultsindicatedthatthe analyzedby of wasconsistentwiththeresultsinthe uptrendhydrolysisyield FSCR； the increasedwithelevatedreaction and hydrolysisyield temperatures increasedreactiontime． TheRaman of or and H20 propertiespureliquidvapor compressed in from100——350。C C02 theFSCRatelevated gas temperaturesranging and50～350。Cwerealso resultsshowed investigated，respectively．The thatwith theRaman of was increased H20 temperature frequency HBW fittedHBSbecameweakerbutthe became increased，the stronger， andboththeHBSandHBWFWHMwidthsbecamenarrowinliquid Raman of wasincreasedwhilethe of H20．The H20 intensity frequency HBW in wasdecreased．andtheFWHMoffitted becamewider H20 Fermiresonancebondsof becameweakerandthe H20．The C02 vapor hotbandsbecame withincreased stronger temperature． 拉曼光谱原位在线检测毛细管反应器中亚临界水水解四氯化碳研究 目 录 第一章前言………………………………………………………………………．．1 1．1选题背景及意义………………………………………………………………1 1．2研究内容………………………………………………………………………2 1．3研究的创新点和难点…………………………………………………………3 第二章文献综述……………………………………………………………………4 2．1超／亚临界水简介……………………………