臭氧催化氧化过程中副产物生成规律研究-市政工程专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - II - Abstract More and more concerns have been paid to the pollution of drinking water sources in recent years. The removal of organic pollutants from drinking water and the control of disinfection by-products (DBPs) have become a crucial problem. Among various technologies used for advanced treatment, catalytic ozonation has good application potentials for water purification. Specially, catalytic ozonation with metal oxides as catalyst is a new technique to improve the ozonation of organic pollutants in water. The FeOOH loaded zeolite and CeO2 loaded Al2O3 were used as the main catalyst in this research. The filtered water from water treatment plant was added with KBr, and then used as the raw water for this research. O3/FeOOH and O3/CeO2 were compared on the formation of ozonation by-products presented by formaldehyde, pyruvic acid, bromate and the control of THMsFP and HAA5FP. Influence effects were investigated and continuous operation was performed. Degradation of UV254 and TOC by O3/CeO2 was more efficient in comparison to O3/FeOOH in filtered water. The formaldehyde production was increased by O3/CeO2 compared to O3 alone while the production of pyruvic acid and bromate was distinctly decreased. As compared with ozonation alone, after O3/FeOOH oxidation, the production of formaldehyde and pyruvic acid were both increased. The concentration of ozone and Br－ mainly affected the production of ozonation by-products. The post treatment as biological carbon filtration is needed to achieve a better water quality. The THMsFP and TCAAFP of filtered water with Br－ was reduced after ozonation, while the DCAAFP increased. The DCAAFP and TCAAFP were reduced by O3/FeOOH comparing to ozonation alone, but the removal of THMsFP had no obvious advantage compared with ozonation alone. The THMsFP was reduced by 43.4% after CeO2 catalytic ozonation than that after ozonation alone, and the DCAAFP/TCAAFP was reduced by 60%. The variati