非微晶硅薄膜太阳电池的衰退及稳定性研究-材料物理与化学专业论文.docxVIP

河北工业大学硕士学位论文 河北工业大学硕士学位论文 非/ 非/微晶硅薄膜太阳电池的衰退及稳定性的研究 i i ii ii 非/微晶硅薄膜太阳电池的衰退及稳定性研究 摘 要 要提高硅基薄膜太阳电池的普及率，必须降低硅基薄膜太阳电池的生产成 本，提高硅基薄膜太阳电池的稳定性及其初始性能。这些因素决定了硅基薄膜太 阳电池的进一步发展，已引起了人们的广泛关注。本文主要以硅基薄膜太阳电池 为研究对象，主要完成了以下工作： 利用改变硅烷浓度和辉光功率制备了一系列低温的单结非晶硅电池及不同 TCO 和衬底温度的 P 型微晶硅单结电池，通过监测光衰退前后的 I-V 变化规律， Raman 光谱以及 SIMS，分析硅薄膜太阳电池的光衰退机理。 制备了不同 I 层厚度和不同电极结构的叠层电池，并将部分电池在红光、白 光和蓝光下进行光照实验。测试光照过程电池光态 J-V 特性，量子效率（QE）及 Raman 谱的变化趋势，探讨了影响叠层太阳电池稳定性的主要原因，寻找最优的 条件。 对单室硅薄膜太阳电池和电池组件的光衰退特性进行了初步研究。通过分析 氢等离子体刻蚀降低硼和磷污染的作用，给出了具有较好稳定性的叠层太阳电池 的氢刻蚀时间,并初步探讨了硅烷浓度对电池组件稳定性的影响。 关键词：非晶硅太阳电池，微晶硅太阳电池，叠层太阳电池，SW 效应，稳定性 STUDY ON THE DEGRADATION AND STABILITY OF AMORPHOUS/MICROCRYSTALLINE SILICON THIN FILM SOLAR CELLS ABSTRACT In order to raise the popularization of silicon solar cells, the producing cost must be reduced and the stabilized conversion efficiency must be improved. Improving the stability of silicon thin film solar cell is as important as improving the initial performance. In this paper, silicon thin film solar cells were investigated. Two kinds of silicon thin film solar cells were prepared to investigate the degradation. One is low temperature single junction based amorphous silicon thin film solar cells were prepared under different silane concentration and power. The other one is P-type single junction based microcrystalline silicon thin film solar cells with different TCO and substrate temperature. The measurements of the I-V、Raman and SIMS were conducted before, during and after light-soaking. The main reason of the degradation of materials was discussed. Tandem silicon thin film solar cells with different I layer and electrode were used to perform light soaking experiments under different light sources. The J-V parameter 、quantum efficiency (QE)and Raman spectroscopy were measured during the light soaking. The degradation of microcrystalline silicon solar cells was studied and finding the optimal parameter. Some preliminary studies on the single-chamber system and tandem module solar cells were inve