纯镁表面有机超疏水层的制备及腐蚀行为-材料工程专业论文.docx

哈尔滨工业大学工程硕士学位论文 哈尔滨工业大学工程硕士学位论文 哈尔滨工业大学工程硕士学位论文 哈尔滨工业大学工程硕士学位论文 万方数据 万方数据 万方数据 万方数据 Abstract Magnesium and magnesium alloy have a series of advantages such as low density, high strength-to - weight ratios, high conductivity, therefore the corrosion protection of Magnesium and magnesium alloy is widely concerned. A good protection method is meaningful to magnesium’s future application. In this paper, a facile one-step process was developed to fabricate superhydrophobic surfaces on the surface of pure Magnesium by cathodic deposition successfully. The electrolyte contains nitrate, myristic acid and ethanol. The process parameters of electrodeposition affect the surface morphology and corrosion resistance significantly. The results of this part experiments were obtained. In the process of electrodeposition, with the time increasing, the layer’s thickness and compactness increased. The improvement of voltage, which leads to higher current density, was helpful to obtain smaller grain size and better compactness. A layer with better corrosion resistance can be obtained by using pulse voltage when other conditions were kept unchanged, comparing to direct voltage. Because pulse voltage can accelerate the transport of charged particles, enhance activation polarization and decrease the concentration polarization, so the nucleation rate can be improved and the defections reduced. The main composition of the layer include calcium myristate and cerium myristate. What’s more, cerium myristate deposits preferentially on the cathode comparing to calcium myristate, because of its smaller radius and higher Charge density. The increasement of Ce content could destroy the layer’s compactness. While, a new method called Dropping process was adopted based on the conclusion above, which effectively combine the high compactness of calcium myristate and the corrosion inhibition of cerium. The experiment results showed that this Dropping Layer had excellent corrosion resis