负载型非晶态催化剂的制备及其加氢脱氧性能的研究-化学工程专业论文.docxVIP

Abstract With the petroleum resources shortage, price rising steadily and people paying attention to environmental problem increasingly, effective usage of fossil resources and developing renewable resources has become a widely concerned research project. Biomass fuel is an ideal substitute because of the compounds containing a few nitrogen and sulfur elements. However, the biological oil is generated by biomass pyrolysis, which contains a lot of oxygen-containing compounds such as acid, aldehyde, ketone, phenol and furan. It leads to the low combustion heat and volatility, poor stability, high viscosity and strong corrosive of the biological oil. Some biological oil can’t be directly used as high grade sources of energy due to the high oxygen content (up to 50 %). Thus the high efficiency and relatively inexpensive catalyst is necessary in order to refine the raw biological oil by hydrodeoxygenation. As a kind of new environmental friendly catalyst, amorphous catalysts are widely used in hydrogenation reaction. Because they possess relatively high activity and selectivity for hydrogenation reaction and other unique properties such as short range order, long range disorder and high degree of unsaturation. However, the amorphous catalysts are invalid in some complicated environment due to the low thermal stability. Thus it is an important research direction for hydrodeoxygenation reaction by amorphous catalyst to improving the thermal stability and chemical stability and preventing crystallization and loss active component of catalyst. Selection and preparation of functional supporter is an effective way to preventing crystallization of catalyst in the process of using. In this paper, Ni-Mo-B/SiO2 amorphous catalysts were prepared by using immersion method and deposition method with reducing agent (NaBH or KBH), active component of catalyst such as La(NO3)3, Ni(NO3)2, (NH4)6Mo7O24 and supporter such as SiO2 or Al2O3. The resulting catalysts were characterized by BET