锆合金析出相的结构特征及形成过程研究-材料加工工程专业论文.docxVIP

万方数据 万方数据 摘要 对比两个合金中的第二相可以发现，都存在 laves 型金属间化合物。结合系 列实验我们可以得出一些共同的特征，即这些 laves 相和基体之间都存在位相关 系，其形核过程都涉及到了晶格切变，而在后期的长大过程中，由于元素扩散 速率不同，不同生长阶段的化学成分会发生变化。这些发现对合金的制备工艺 选择提供了参考。 关键词：第二相；晶体结构；位向关系；δ 氢化物；孪晶；生长规律 II Abst Abstract abstract Zirconium alloy have excellent mechanical properties, corrosion resistance, and good compatibility with reactor fuel. Therefore it is suitable for nuclear reactor cladding and structural materials, and has been a hot topic of nuclear material. Nowadays countries promote the development of new zirconium alloy by adjusting the composition of alloys as well as improving the process. In this process, type, quantity, size distribution and other characteristics of the precipitates in alloys have significantly changed. These changes have a significant impact on the mechanical properties, high temperature water resistance, creep resistance, anti-radiation properties of the alloys. Therefore, it is important to critically study the feature of precipitates in the zirconium alloy including crystal structure, composition, defects, and growth law. In this work, precipitates of widely used Zr-4 alloy and Zirlo alloy were comprehensively and thoroughly characterised. Precipitates were also melted to further expanding the size of the scope in this study. In addition, a series of experiments also examined the primarily form of zirconium hydride in zirconium alloys. Its internal structure was analyzed combined with its morphology, which drawed some meaningful conclusions. It was found that there are more than one type of second phase in Zr-4 alloy, including C14, C15-type laves phase and Zr-Fe-Ni tetragonal phase. Comparing the orientation relationship and atomic mismatch between matrix and these two laves phase, we hypothesized that the normal stable state of the laves phase is C14 structure. Through the HRTEM analysis of C14 second phase, the long-period structure has been associated with the presence of its internal stacking fault on certain crystal planes.