锆盐体系电解液失效过程研究-材料加工专业论文.docxVIP

摘 要 本文以 AZ91D 镁合金为试验基材，锆盐体系电解液为基础溶液进行微弧氧化处理， 研究了随着加工过程的进行电解液的衰变规律以及对衰变过程电解液对所加工试样综 合性能的影响。然后期通过一定的方法尝试对失效溶液再生，对再生电解液和原电解液 的加工性能通过试样的微观形貌进行对比分析，探讨了再生过程的机理及未来的发展可 能性。通过试验分析了电解液 pH 值、电导率、温度变化值对电解液随使用过程失效的 变化规律，对所加工试样的耐蚀性、致密度和微观形貌、相组成随失效过程所受影响进 行观察，分析。实验发现:失效过程引起电解液的 pH 值升高，电导率增强，温度变化值 降低；试样耐蚀性先下降后上升，致密度先上升后下降，而膜层微观腐蚀形貌，相组成 几乎没有发生变化。尝试了已经失效的溶液采用过滤、添加改良剂的办法进行再生，结 果表明过滤的方法对老化电解液具有一定作用，但不能有效改善失效电解液；而添加改 良剂能够很好地改善失效的电解液，所加工试样与原电解液相比还存在一定差距，有待 进一步深入研究。 微弧氧化一旦开始进行，电解液中的成分即发生改变（主要是试样的基体成分在反 应过程中以杂质形态进入电解液，造成电解液污染），随着加工过程的进行电解液通常 也会变得不稳定，伴随的现象首先是溶液内部出现浑浊,随后底部有絮状沉淀析出，起 弧电压升高、弧点变大，所加工的试样从表面光洁完整到局部粗糙甚至出现麻点，电解 液使用的时间越长（加工工件越多）这种现象越明显。说明微弧氧化过程改变了电解液 的性质，同时对所加工试样性能造成影响，而这个过程是无法避免的。本试验在一定量 电解液中采用固定电参数研究溶液失效问题，当电解液无法起弧或者试样产生宏观缺陷 来确定电解液的失效。 关键词：镁合金，微弧氧化，电解液失效，耐蚀性 i ii ii Abstract In this paper the AZ91D magnesium alloy was treated by micro arc oxidation technology in zirconium salt solution system. The decay law of electrolyte and the influence on the performance of samples was studied. A certain methods was attempted at the end of the experiment of solution regeneration failure. The machine bility of regeneration of electrolyte and electrolyte through the microstructure were compared and analyzed, discuss the regeneration mechanism and future possibilities for the future development. The mechanism and regeneration of failure electrolyte was also discussed. The pH, conductivity, temperature variation of electrolyte was analyzed in the failure process, the impact of specimens’ properties contain corrosion resistance, density, phase composition and morphology were observed and analyzed. Experiments show that: the failure process caused the pH value increased, the conductivity raised, temperature decreased; the corrosion resistance first decreased and then increased, the density increased first and then decreased, while the film appeared micro morphology corrosion, phase composition almost has no change. Try to revive the disabled solution by filtering or additive. It is found that the f