风电叶片材料双酚F环氧树脂的合成研究化学工程专业论文.docxVIP

ii ii Abstract Wind power generate electricity is encouraged by the state and in urgent need of energy saving and environmental protection projects. Wind turbine blades work outdoors，so it need a higher request in the something of sustain Strong wind load, sand erosion, ultraviolet radiation, atmospheric oxidation and corrosion, acid corrosion, material costs. Now wind turbine blades MW have used carbon fiber reinforced epoxy resin composite material, The epoxy resin which need requirements of low viscosity, good fiber immersion, high impact resistance, good toughness. But general-purpose resin(bisphenol A epoxy resin) with high viscosity, impact resistance and poor weatherability, coats in outdoor easy to powder and light and less loss of fullness, not suitable for outdoor use of coatings and adhesives.So R D of new wind power blades resin has very important significance. New type of bisphenol F epoxy resin with low viscosity, solvent resistance, and high impact resistance, and impregnation of the fiber and glass fiber reinforced plastic composite performance, the use of low cost has b een good for the manufacture of wind power blade-based system for materials. The main raw material for bisphenol F has been in foreign production, However, the presence of high phenol / formaldehyde ratio, the performance of the best isomers of low-bit, low yield, a product of complex issues such as post-processing,and the use of a large cycle of evaporation to apply a multiple of phenol and reaction conditions in the heated, resulting in higher production costs. The high price of imports of bisphenol F, bisphenol F epoxy resin resulted in the domestic production of small -scale. Bisphenol F epoxy resin was prepared in a two-step process by using phenol, formaldehyde, epichlorohydrin etc. as raw materials. Firstly, biphenol F was synthesized by electrophilic substitution reaction of phenol with formaldehyde in the presence of phosphoric acid catalyst and methanol solvent. T