改性蒙脱石脱酚脱氨效果及其处理焦化废水的试验研究-环境科学与工程专业论文.docx

Classified Index: X703.1 U.D.C: 628.35 Dissertation for the Master Degree in Engineering EXPERIMENTAL STUDY ON ADSORPTION OF MODIFIED MONTMORILLONITE FOR PHENOL, AMMONIA-NITROGEN AND COKING WASTE WATER Candidate：Zhao Jianwei Candidate： Zhao Jianwei Supervisor： Prof. Huang Ju Academic Degree Applied for： Master of Engi Specialty： Environmental Affiliation： School of Mun Date of Defence： July，2007 Degree-Conferring-Institution： Harbin Institut Science and Engineering Engineering icipal and Environmental e of Technology 哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 - - I - 摘要 焦化废水作为一种难处理废水一直倍受国内外学者关注，目前主要的处 理方法有物化法、生化法和高级氧化法。本文是在生化处理为主要处理工艺 的基础上，将改性蒙脱石用于对焦化废水进行深度处理和预处理，取得了积 极的研究成果，具有重要的理论意义和实用价值。 在汲取国内外对蒙脱石改性研究方面先进成果的基础上，本文深入研究 了蒙脱石有机改性的方法和条件，制备了多种改性蒙脱石，系统研究了有机 改性和钠化改型对蒙脱石性能和结构的影响，并采用 XRD、IR、SEM 等手 段对有机蒙脱石和钠基蒙脱石进行了表征。 本文系统深入地研究了改性蒙脱石对水中苯酚和氨氮的去除效果和影响 因素。确定了改性蒙脱石脱酚脱氨的最佳工艺参数，试验研究表明有机蒙脱 石对苯酚和钠基蒙脱石对氨氮的吸附符合 Freundlich 吸附等温式；对吸附模 型的验证结果表明，Freundlich 吸附等温式可以很好地描述有机蒙脱石对苯 酚和钠基蒙脱石对氨氮的吸附过程；对有机蒙脱石吸附苯酚的动力学研究表 明反应很容易进行。 根据焦化废水水质和改性蒙脱石对污染物的吸附特性，制备了复合吸附 混凝剂，并将其应用于焦化废水深度处理和预处理，确定其工艺条件并考察 其处理效果，试验结果表明由改性蒙脱石和聚合氯化铝混合而成的吸附混凝 剂可以极大地降低后续处理的负荷，具有广泛的应用前景。 关键词 改性蒙脱石；吸附；焦化废水 - - II - Abstract As a kind of unwieldiness wastewater, cocking wastewater always receives attention from many researchers. Up to now, there are three treatment methods which are physicochemical treatment, biochemical treatment and advanced oxidation processes. In this paper, modified montmorillonite is used in both advanced treatment and pretreatment of cocking wastewater based on biochemical process. Many achievements that are of great significance and practical value have been made. In foundation of drawing advanced experiences in the modification of montmorilllonite from china and abroad, the author discussed the conditions and methods of organic modification. Many kinds of modified montmorillonite was prepared and the influence of organic modification and sodium-modification on properties and structures of the modified montmorillon