赣南某低品位钨锡矿石综合回收工艺研究-矿物加工工程专业论文.docxVIP

江西理工大学硕士学位论文 江西理工大学硕士学位论文 摘要 万方数据 万方数据 摘 要 随着钨锡富矿资源的不断减少，贫、细、杂钨锡矿产资源逐渐成为主流，难选钨锡 矿石选矿新技术新工艺应运而生。本文以赣南某矿深部云英岩浸染型低品位钨锡矿石为 研究对象，通过试验综合回收矿石中钨、锡矿物及伴生金属硫化矿的研究成果。矿石属 浸染型低品位难选钨锡矿石。钨以黑钨矿、锡以锡石产出，钼、铋、铜、锌均以硫化矿 形式存在。有价组分含量低、种类多且呈分散分布是其主要特点；黑钨矿和锡石呈中细 粒不均匀嵌布，相比而言锡粗钨细；而硫化矿物的嵌布粒度介于细粒和微细粒间的范畴。 本文通过方案比较，采用全浮主干流程即，硫化矿混浮—钨锡混合粗选抛尾，钨锡 粗精矿摇床精选—钨锡磁选分离，摇床中矿集中处理，最后获黑钨精矿和锡石精矿。当 试样含 WO30.179%、Sn0.107%，磨矿细度-0.074mm 占 70%时，全流程综合试验获钨精 矿含 WO365.11%，钨回收率 83.25%，锡精矿含 Sn44.91%，锡回收率为 83.35%，硫化 矿混合精矿定时集中分选。精矿质量分析结果，钨精矿质量达到Ⅰ类一级品标准；锡精 矿质量达到Ⅰ类六级品要求。 采用全浮主干流程回收钨锡及伴生硫化矿有以下优点：主干流程作业线短、抛尾快； 设备占地少、配置简单、基建投资小；对矿石的适应性强、分选效率高、指标好；工艺 成熟、便于操作管理。 采用 731 氧化石蜡皂+苄基砷酸组合作钨锡混浮捕收剂是本文的特点。结合试验数 据对组合药剂作用于钨锡矿石表面的机理进行分析与探讨发现，731 对黑钨矿的捕收能 力大于苄基砷酸，苄基砷酸捕收锡石的能力大于 731；两种药剂加入的先后顺序对正协 同效应的大小有影响，先加入捕收能力强的或者同时加入两种捕收剂有利于产生正的协 同效应。 关键词：浮选；钨锡混浮；磁选分离；协同效应 I Ab Abstract Abstract With the continuous reduction of tungsten-tin ore resources, The poor, small, miscellaneous tungsten tin mineral resources become mainstream gradually, the new technologies and new research on refractoring tungsten-tin emerged. In this paper, the study object is a deep greisen disseminated low grade tungsten-tin ore of Gannan. Obtain research result on comprehensive recovery of tungsten-tin ore and associated metals through the test. Disseminated ore is refractory low-grade tungsten-tin ore. Tungsten is mainly wolframite, tin is mainly cassiterite, and molybdenum, bismuth, copper, zinc all in the form of sulfide ore. The main feature of ore is that the content of useful components is lowly, variety and a dispersed distribution. Wolframite and cassiterite were disseminated in fine uneven, compared with coarse fine tungsten tin; and disseminated sulfide minerals and micro-fine particle size between areas between fine. Through a variety of programs compared, make flotation as the main process, the process is sulphide ore flotation - tin-tungsten mixed rougher tailing, selected coarse tungsten concentrate shaker tin - tungsten, tin magnetic separation, shaker ore concent