赣南脐橙园土壤重金属形态分析与污染评价-无机化学专业论文.docxVIP

赣南师 赣南师范学院硕士学位论文 II II 样品的土壤重金属的形态进行了分析，研究了果园土壤中不同重金属元素的污染来源和形态 分布特征。结果表明：不同类型土壤中重金属元素 Ni、Cu、Cr、Zn 和 Pb 均以残渣态为主； 各元素在四种类型土壤中的含量和形态分布规律基本一致；重金属元素的活性态所占比例从 高到低依次为：Pb＞Cu＞Zn＞Ni＞Cr，总体而言，五种重金属元素的潜在环境风险都较小， 而 pH 是影响土壤重金属赋存形态的重要因素。 关键词：果园土壤；重金属；形态；地积累指数；潜在生态风险指数 III III Abstract With the rapid development of socio-economic, heavy metal pollutionin in soil has received increasing attention. Wastes containing harmful heavy metals released into the soils, resulting in the deterioration of soil quality of the environment, affecting crop growth and development, resulting in a decline in yield and quality of agricultural products, and can cause harm to other organisms and human health through the food chain. Total metal analysis can not effectively provide may provide the environmental impact due to their mobilizable characteristics and varied bioavailability to plants. Therefore, it is important to study heavy metals in the soil for understanding their change version and potential environmental risk. In this paper, the soil samples from navel orange orchards located in the 18 counties of Ganzhou city were regarded as research object. Base on the analysis of the content of heavy metals (Hg, As, Pb, Cd, Zn, Ni, Cr and Cu), the pollution of heavy metals in soil in Ganzhou suburbs is evaluated on the basis of the index of geoaccumulation and the potential ecological risk index. The potential sources and the distribution of heavy metals are studied. Overall, the BCR three-step sequential extraction procedure was applied to fractionate heavy metals and the concentrations of Ni, Cu, Cr, Zn and Pb in various extracts solutions were analyzed by Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES). The chemical speciation distribution and the pollution influence of heavy metal in Ganzhou city soil were discussed. The main contents of the study as follows: Chapter one, the progress of the heavy metal, evaluation methods and the chemical speciation distribution are summarized.