冬季APEC峰会前后室内外VOCs相关性分析.PDF

中国环境科学 2015,35(11) ：3201~3210 China Environmental Science 冬季 APEC 峰会前后室内外 VOCs 相关性分析 吴亚涛,刘兆荣* (北京大学环境科学与工程学院,北京 100871) 摘要：为研究冬季 VOCs 类物质的室内外相关性,于 2014 年 11 月 5 日~12 月 11 日对一间无人为活动的房间的空气进行了室内外同步采 样,定量分析了 98 种 VOCs 物质,并将其分为烷烃、烯烃、芳香烃、卤代烃和含氧烃五类,分别讨论了 VOCs 的浓度水平、I/O 、室内外相 关系数和分类间的相关系数,并利用质量平衡模型初步估计了室外源对室内 VOCs 的贡献情况.研究表明,五类 VOCs 的室内浓度均大于室 外浓度,且烷烃含氧烃 卤代烃烯烃;五类 VOCs 均同时存在室内源和室外源;对于 VOCs 的室内外相关性,烯烃和含氧烃分别为相关性最 差和最好的组分, 同时,r( 卤代烃)r(烷烃)r(芳香烃);对于物质间的相关性,烷烃-烯烃的相关性在室内外均最高(rin=0.805,rout=0.888,P≤0.01), 卤代烃-含氧烃之间的相关性最差(rin=0.491,P≤0.05;rout=0.529,P≤0.01);室外源对室内浓度的贡献率与 VOCs 的种类相关,贡献率均值最高的 是卤代烃类(56.57%),之后依次是烷烃(46.64%)、烯烃(40.10%)、含氧烃(33.98%)和芳香烃(20.67%).此外,APEC 峰会后 VOCs 的浓度水平、 I/O 、室内外相关性以及物质间的相关性均高于峰会前的对应值. 关键词：VOCs ；室内外相关性；I/O ；室外贡献率；APEC 中图分类号：X511 文献标识码：A 文章编号：1000-6923(2015)11-3201-10 * Relationship between indoor and outdoor VOCs bofore and after APEC summit. WU Ya-tao, LIU Zhao-rong (College of Environmental Sciences and Engineering, Peking University, Beijing 100871, China). China Environmental Science, 2015,35(11)：3201~3210 Abstract ：To investigate the relationship between indoor and outdoor VOCs, the air in and out of an idle room were simultaneously sampled from Nov.5 to Dec.11, 2014. 98 kinds of VOCs were quantitated and discussed by dividing them into five categories according to their functional groups, and they are alkanes, olefin, aromatics, halogen and oxygenated hydrocarbons, respectively. In this paper, we disicussed the concentration levels, I/O, indoor and outdoor relevance as well as the correlation between different categories of VOCs. At last, we roughly estimated the contribution of outdoor VOCs sources on indoor VOCs concentration. Results showed that indoor VOCs had higher concentritions than out